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Functional Liquid Metal Nanoparticles Produced by Liquid-Based Nebulization

Functional Liquid Metal Nanoparticles Produced by Liquid-Based Nebulization
Functional Liquid Metal Nanoparticles Produced by Liquid-Based Nebulization

Functional liquid metal nanoparticles (NPs), produced from eutectic alloys of gallium, promise new horizons in the fields of sensors, microfluidics, flexible electronics, catalysis, and biomedicine. Here, the development of a vapor cavity generating ultrasonic platform for nebulizing liquid metal within aqueous media for the one-step production of stable and functional liquid metal NPs is shown. The size distribution of the NPs is fully characterized and it is demonstrated that various macro and small molecules can also be grafted onto these liquid metal NPs during the liquid-based nebulization process. The cytotoxicity of the NPs grafted with different molecules is further explored. Moreover, it is shown that it is possible to control the thickness of the oxide layer on the produced NPs using electrochemistry that can be embedded within the platform. It is envisaged that this platform can be adapted as a cost-effective and versatile device for the rapid production of functional liquid metal NPs for future liquid metal-based optical, electronic, catalytic, and biomedical applications.

EGaIn, functional material, liquid metal, nanoparticle, nebulization
2365-709X
Tang, Shi Yang
1d0f15c6-2a3e-4bad-a3d8-fc267db93ed4
Qiao, Ruirui
cf0ce629-af33-47c2-81c5-6d62ccf80f7e
Lin, Yiliang
e6d919e1-9c9f-4600-a4e6-49b0672509d4
Li, Yuhuan
920bae00-6d57-4b1f-bd3c-9fe7b13e9eb2
Zhao, Qianbin
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Yuan, Dan
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Yun, Guolin
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Guo, Jinhong
d65d7044-32c8-4028-a6b3-d221ad8bf006
Dickey, Michael D.
5fe7588c-05b3-4e27-a023-e9a5cb72a305
Huang, Tony Jun
d380fbd6-4484-46b2-96f9-6cfec83ecae6
Davis, Thomas P.
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Kalantar-Zadeh, Kourosh
aded6a64-8612-40b7-aae9-233fbae916a6
Li, Weihua
e2555036-0e48-425a-afeb-db6ffba5238e
Tang, Shi Yang
1d0f15c6-2a3e-4bad-a3d8-fc267db93ed4
Qiao, Ruirui
cf0ce629-af33-47c2-81c5-6d62ccf80f7e
Lin, Yiliang
e6d919e1-9c9f-4600-a4e6-49b0672509d4
Li, Yuhuan
920bae00-6d57-4b1f-bd3c-9fe7b13e9eb2
Zhao, Qianbin
4e956b7f-4fb6-42fa-9a3b-b9a7c3703493
Yuan, Dan
76b9b77e-dda5-4682-8db0-75bfad1d1258
Yun, Guolin
240c3dc9-c224-41c0-8740-de165d1eb90b
Guo, Jinhong
d65d7044-32c8-4028-a6b3-d221ad8bf006
Dickey, Michael D.
5fe7588c-05b3-4e27-a023-e9a5cb72a305
Huang, Tony Jun
d380fbd6-4484-46b2-96f9-6cfec83ecae6
Davis, Thomas P.
1041ec19-c740-4a43-bbaf-e8a740c2f658
Kalantar-Zadeh, Kourosh
aded6a64-8612-40b7-aae9-233fbae916a6
Li, Weihua
e2555036-0e48-425a-afeb-db6ffba5238e

Tang, Shi Yang, Qiao, Ruirui, Lin, Yiliang, Li, Yuhuan, Zhao, Qianbin, Yuan, Dan, Yun, Guolin, Guo, Jinhong, Dickey, Michael D., Huang, Tony Jun, Davis, Thomas P., Kalantar-Zadeh, Kourosh and Li, Weihua (2019) Functional Liquid Metal Nanoparticles Produced by Liquid-Based Nebulization. Advanced Materials Technologies, 4 (2), [1800420]. (doi:10.1002/admt.201800420).

Record type: Article

Abstract

Functional liquid metal nanoparticles (NPs), produced from eutectic alloys of gallium, promise new horizons in the fields of sensors, microfluidics, flexible electronics, catalysis, and biomedicine. Here, the development of a vapor cavity generating ultrasonic platform for nebulizing liquid metal within aqueous media for the one-step production of stable and functional liquid metal NPs is shown. The size distribution of the NPs is fully characterized and it is demonstrated that various macro and small molecules can also be grafted onto these liquid metal NPs during the liquid-based nebulization process. The cytotoxicity of the NPs grafted with different molecules is further explored. Moreover, it is shown that it is possible to control the thickness of the oxide layer on the produced NPs using electrochemistry that can be embedded within the platform. It is envisaged that this platform can be adapted as a cost-effective and versatile device for the rapid production of functional liquid metal NPs for future liquid metal-based optical, electronic, catalytic, and biomedical applications.

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More information

Published date: 1 February 2019
Additional Information: Funding Information: S.-Y.T. and R.Q. contributed equally to this work. S.-Y.T. is the recipient of the Vice Chancellor's Postdoctoral Research Fellowship funded by the University of Wollongong. T.P.D. and R.Q. were supported by the Australian Research Council Centre of Excellence in Convergent Bio-Nano Science and Technology (Project No. CE140100036). M.D.D. gratefully acknowledges support from the NSF (CMMI-0954321) and NSF Research Triangle MRSEC on Programmable Soft Matter (DMR-1121107). The authors acknowledge use of the facilities and the assistance of Dr. David Mitchell at the UOW Electron Microscopy Centre. Funding Information: S.-Y.T. and R.Q. contributed equally to this work. S.-Y.T. is the recipient of the Vice Chancellor’s Postdoctoral Research Fellowship funded by the University of Wollongong. T.P.D. and R.Q. were supported by the Australian Research Council Centre of Excellence in Convergent Bio-Nano Science and Technology (Project No. CE140100036). M.D.D. gratefully acknowledges support from the NSF (CMMI-0954321) and NSF Research Triangle MRSEC on Programmable Soft Matter (DMR-1121107). The authors acknowledge use of the facilities and the assistance of Dr. David Mitchell at the UOW Electron Microscopy Centre. Publisher Copyright: © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Keywords: EGaIn, functional material, liquid metal, nanoparticle, nebulization

Identifiers

Local EPrints ID: 481711
URI: http://eprints.soton.ac.uk/id/eprint/481711
ISSN: 2365-709X
PURE UUID: 62142125-32b0-43fa-9604-47fb71e8f81d
ORCID for Shi Yang Tang: ORCID iD orcid.org/0000-0002-3079-8880

Catalogue record

Date deposited: 06 Sep 2023 16:50
Last modified: 06 Jun 2024 02:18

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Contributors

Author: Shi Yang Tang ORCID iD
Author: Ruirui Qiao
Author: Yiliang Lin
Author: Yuhuan Li
Author: Qianbin Zhao
Author: Dan Yuan
Author: Guolin Yun
Author: Jinhong Guo
Author: Michael D. Dickey
Author: Tony Jun Huang
Author: Thomas P. Davis
Author: Kourosh Kalantar-Zadeh
Author: Weihua Li

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