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Liquid metal hybrid composites with high-sensitivity and large dynamic range enabled by micro- and macrostructure engineering

Liquid metal hybrid composites with high-sensitivity and large dynamic range enabled by micro- and macrostructure engineering
Liquid metal hybrid composites with high-sensitivity and large dynamic range enabled by micro- and macrostructure engineering

Conductive elastic composites composed of conductive fillers and polymer matrices are showing an increasing number of applications in the fields of flexible sensors, wearable devices, and stretchable electronics. Under mechanical deformation, the conductive filler network in the matrix shifts to change the conductive pathway among particles and thus, electrical conductivity of the composite. For most conductive composites, their conductivity changes monotonically with strain. Here, we report a composite that exhibits an unconventional strain response; its electrical conductivity increases sharply under both compressive and tensile loads. The Ecoflex-based composite contains spike-shaped nickel microparticles and liquid metal microdroplets. Because of the elastomeric mechanical properties of Ecoflex, the composite has an extremely high stretchability and pressure sensitivity, which is ideal for tactile sensing and mechanical responsiveness. On the basis of a composite film with a grooved or pyramidal surface structure, we demonstrate a pressure-controlled intelligent heating film and a pressure sensor with extremely high sensitivity and dynamic range.

conductive elastomer, high sensitivity flexible sensor, liquid metal, multiscale structure design, stretchable electronics
2637-6105
5302-5315
Yun, Guolin
240c3dc9-c224-41c0-8740-de165d1eb90b
Tang, Shi Yang
1d0f15c6-2a3e-4bad-a3d8-fc267db93ed4
Lu, Hongda
731b3c09-82ae-408b-8218-95b0de29f2dd
Cole, Tim
78cebdf5-e360-4e8e-9dea-ba4b88306980
Sun, Shuaishuai
94afa956-f4bc-44b5-a5ce-23850fd51eda
Shu, Jian
10c82f94-8f99-4785-b33f-fa20484344fd
Zheng, Jiahao
44791733-cef3-4cca-9e18-1779b64e3b84
Zhang, Qingtian
58f0e671-0e53-478f-8f4d-b94dd720893e
Zhang, Shiwu
da008f91-71fa-42fb-879e-68b91429e1d6
Dickey, Michael D.
5fe7588c-05b3-4e27-a023-e9a5cb72a305
Li, Weihua
e2555036-0e48-425a-afeb-db6ffba5238e
Yun, Guolin
240c3dc9-c224-41c0-8740-de165d1eb90b
Tang, Shi Yang
1d0f15c6-2a3e-4bad-a3d8-fc267db93ed4
Lu, Hongda
731b3c09-82ae-408b-8218-95b0de29f2dd
Cole, Tim
78cebdf5-e360-4e8e-9dea-ba4b88306980
Sun, Shuaishuai
94afa956-f4bc-44b5-a5ce-23850fd51eda
Shu, Jian
10c82f94-8f99-4785-b33f-fa20484344fd
Zheng, Jiahao
44791733-cef3-4cca-9e18-1779b64e3b84
Zhang, Qingtian
58f0e671-0e53-478f-8f4d-b94dd720893e
Zhang, Shiwu
da008f91-71fa-42fb-879e-68b91429e1d6
Dickey, Michael D.
5fe7588c-05b3-4e27-a023-e9a5cb72a305
Li, Weihua
e2555036-0e48-425a-afeb-db6ffba5238e

Yun, Guolin, Tang, Shi Yang, Lu, Hongda, Cole, Tim, Sun, Shuaishuai, Shu, Jian, Zheng, Jiahao, Zhang, Qingtian, Zhang, Shiwu, Dickey, Michael D. and Li, Weihua (2021) Liquid metal hybrid composites with high-sensitivity and large dynamic range enabled by micro- and macrostructure engineering. ACS Applied Polymer Materials, 3 (10), 5302-5315. (doi:10.1021/acsapm.1c01111).

Record type: Article

Abstract

Conductive elastic composites composed of conductive fillers and polymer matrices are showing an increasing number of applications in the fields of flexible sensors, wearable devices, and stretchable electronics. Under mechanical deformation, the conductive filler network in the matrix shifts to change the conductive pathway among particles and thus, electrical conductivity of the composite. For most conductive composites, their conductivity changes monotonically with strain. Here, we report a composite that exhibits an unconventional strain response; its electrical conductivity increases sharply under both compressive and tensile loads. The Ecoflex-based composite contains spike-shaped nickel microparticles and liquid metal microdroplets. Because of the elastomeric mechanical properties of Ecoflex, the composite has an extremely high stretchability and pressure sensitivity, which is ideal for tactile sensing and mechanical responsiveness. On the basis of a composite film with a grooved or pyramidal surface structure, we demonstrate a pressure-controlled intelligent heating film and a pressure sensor with extremely high sensitivity and dynamic range.

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More information

Published date: 8 October 2021
Additional Information: Funding Information: The authors acknowledge use of the facilities at the Instruments’ Center for Physical Science (USTC), Micro/Nano Engineering Laboratory (USTC), and the Experimental Center of Engineering and Material Sciences (USTC). S.-Y.T. is grateful for the support from the Royal Society (IEC\NSFC\201223), UK. Publisher Copyright: © 2021 American Chemical Society.
Keywords: conductive elastomer, high sensitivity flexible sensor, liquid metal, multiscale structure design, stretchable electronics

Identifiers

Local EPrints ID: 481766
URI: http://eprints.soton.ac.uk/id/eprint/481766
ISSN: 2637-6105
PURE UUID: 2b17d3f2-46b3-40d4-9bbb-c79462d111ba
ORCID for Shi Yang Tang: ORCID iD orcid.org/0000-0002-3079-8880

Catalogue record

Date deposited: 07 Sep 2023 16:35
Last modified: 18 Mar 2024 04:13

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Contributors

Author: Guolin Yun
Author: Shi Yang Tang ORCID iD
Author: Hongda Lu
Author: Tim Cole
Author: Shuaishuai Sun
Author: Jian Shu
Author: Jiahao Zheng
Author: Qingtian Zhang
Author: Shiwu Zhang
Author: Michael D. Dickey
Author: Weihua Li

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