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Poplar wood torrefaction: kinetics, thermochemistry and implications

Poplar wood torrefaction: kinetics, thermochemistry and implications
Poplar wood torrefaction: kinetics, thermochemistry and implications

The kinetic and thermochemical models for poplar wood torrefaction were developed in the present work. The torrefaction kinetic model satisfactorily fitted the experimental thermogravimetric analysis (TGA) data of poplar wood torrefaction and provided a coherent description of the evolution of torrefaction volatile and solid products in terms of a set of identifiable chemical components and elemental compositions. The torrefaction thermochemical model described the thermochemical performance of poplar wood torrefaction processes. The results from the kinetic and thermochemical models for poplar wood torrefaction showed that (1) high temperature increases the evolution rate of torrefaction products, and favors the formation of torrefaction volatiles; (2) the heating rate has a slight effect on evolution for torrefaction process; (3) the mass and energy yields of torrefaction products are significantly influenced by both torrefaction temperature and residence time; (4) the heat of torrefaction reaction is mostly endothermic with a relatively small amount (less than 10% of the raw material energy content); (5) for the overall torrefaction processes, the sensible and latent energy of torrefaction products accounts for 5–18% of the total energy input and the remaining energy input transfers into the energy contents of torrefaction products. This work provides a theoretical guidance for future evaluation and optimization of woody biomass torrefaction systems/processes, and thereafter for the industrial application of woody biomass thermochemical conversion.

Energy balance, Kinetics, Thermochemistry, Torrefaction, Woody biomass
1364-0321
Chai, Meiyun
1daa6ce6-e557-456d-b5cc-ea3e98dd8538
Xie, Li
38c75fe3-02e0-418c-a058-b8130450b0ee
Yu, Xi
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Zhang, Xingguang
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Yang, Yang
4f250291-4405-49b3-a662-eb9810e00415
Rahman, Md Maksudur
e18e7868-17cf-45f3-aa90-c5b96707debe
Blanco, Paula H.
95da2984-781a-45ae-a410-7d6472cd275b
Liu, Ronghou
f0b96144-766a-453a-a9d9-daeef6dfaf1b
Bridgwater, Anthony V.
0bb8f904-9940-4063-a29c-4b8c006786b1
Cai, Junmeng
9e5ac5c2-f617-4571-a0f5-687670340568
Chai, Meiyun
1daa6ce6-e557-456d-b5cc-ea3e98dd8538
Xie, Li
38c75fe3-02e0-418c-a058-b8130450b0ee
Yu, Xi
7e4f553f-cc11-4c6e-ad6d-9fb5c3c07a60
Zhang, Xingguang
98a45d36-518b-4f6f-ac05-b47b277ddc10
Yang, Yang
4f250291-4405-49b3-a662-eb9810e00415
Rahman, Md Maksudur
e18e7868-17cf-45f3-aa90-c5b96707debe
Blanco, Paula H.
95da2984-781a-45ae-a410-7d6472cd275b
Liu, Ronghou
f0b96144-766a-453a-a9d9-daeef6dfaf1b
Bridgwater, Anthony V.
0bb8f904-9940-4063-a29c-4b8c006786b1
Cai, Junmeng
9e5ac5c2-f617-4571-a0f5-687670340568

Chai, Meiyun, Xie, Li, Yu, Xi, Zhang, Xingguang, Yang, Yang, Rahman, Md Maksudur, Blanco, Paula H., Liu, Ronghou, Bridgwater, Anthony V. and Cai, Junmeng (2021) Poplar wood torrefaction: kinetics, thermochemistry and implications. Renewable and Sustainable Energy Reviews, 143, [110962]. (doi:10.1016/j.rser.2021.110962).

Record type: Article

Abstract

The kinetic and thermochemical models for poplar wood torrefaction were developed in the present work. The torrefaction kinetic model satisfactorily fitted the experimental thermogravimetric analysis (TGA) data of poplar wood torrefaction and provided a coherent description of the evolution of torrefaction volatile and solid products in terms of a set of identifiable chemical components and elemental compositions. The torrefaction thermochemical model described the thermochemical performance of poplar wood torrefaction processes. The results from the kinetic and thermochemical models for poplar wood torrefaction showed that (1) high temperature increases the evolution rate of torrefaction products, and favors the formation of torrefaction volatiles; (2) the heating rate has a slight effect on evolution for torrefaction process; (3) the mass and energy yields of torrefaction products are significantly influenced by both torrefaction temperature and residence time; (4) the heat of torrefaction reaction is mostly endothermic with a relatively small amount (less than 10% of the raw material energy content); (5) for the overall torrefaction processes, the sensible and latent energy of torrefaction products accounts for 5–18% of the total energy input and the remaining energy input transfers into the energy contents of torrefaction products. This work provides a theoretical guidance for future evaluation and optimization of woody biomass torrefaction systems/processes, and thereafter for the industrial application of woody biomass thermochemical conversion.

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More information

e-pub ahead of print date: 24 March 2021
Published date: 24 March 2021
Additional Information: Funding Information: Financial support from Sino-German Center for Research Promotion (Grant No.: M − 0183 ), Guangdong Provincial Key Laboratory of Distributed Energy Systems (Grant No.: 2020B1212060075 ), and CAS Key Laboratory of Renewable Energy (No. Y807k91001 ) is greatly acknowledged. Publisher Copyright: © 2021 Elsevier Ltd
Keywords: Energy balance, Kinetics, Thermochemistry, Torrefaction, Woody biomass

Identifiers

Local EPrints ID: 481880
URI: http://eprints.soton.ac.uk/id/eprint/481880
ISSN: 1364-0321
PURE UUID: 83d4928c-771a-49d6-aac8-7709c72d9152

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Date deposited: 12 Sep 2023 16:41
Last modified: 18 Mar 2024 04:14

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Contributors

Author: Meiyun Chai
Author: Li Xie
Author: Xi Yu ORCID iD
Author: Xingguang Zhang
Author: Yang Yang
Author: Md Maksudur Rahman
Author: Paula H. Blanco
Author: Ronghou Liu
Author: Anthony V. Bridgwater
Author: Junmeng Cai

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