Synthesis of enantiomerically pure and racemic benzyl-tethered Ru(II)/TsDPEN complexes by direct arene substitution: further complexes and applications
Synthesis of enantiomerically pure and racemic benzyl-tethered Ru(II)/TsDPEN complexes by direct arene substitution: further complexes and applications
The use of a direct arene-exchange method for the synthesis of benzyl-tethered arene/Ru/TsDPEN complexes for use in asymmetric transfer hydrogenation is reported. A series of complexes tethered through a three-carbon linear chain was also prepared. The arene-exchange approach significantly simplifies the synthetic approach to this class of catalyst and permits the ready formation of modified analogues. The approach also provides a route to racemic catalysts for use in general reductions with either hydrogen or transfer hydrogenation.
48-64
Soni, Rina
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Jolley, Katherine E.
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Gosiewska, Silvia
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Clarkson, Guy J.
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Fang, Zhijia
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Hall, Thomas H.
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Treloar, Ben N.
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Knighton, Richard C.
5a63128e-0ebd-466a-b327-3aee6e85a76d
Wills, Martin
4529569b-d977-463d-a99f-fccec46e21a0
8 January 2018
Soni, Rina
bb11d9e7-dadc-41aa-aa50-e051a246e0ba
Jolley, Katherine E.
c2bbafc9-c814-4183-b56f-6235474ae1d9
Gosiewska, Silvia
bb905717-b934-47bc-8f93-4c1c8a0bd575
Clarkson, Guy J.
ee6d1c2a-c9f7-4f0b-a28c-f91a35bccf49
Fang, Zhijia
9fb7dff6-1a1a-46f8-96b4-3430ca18d0ec
Hall, Thomas H.
3f66601a-bac5-46b6-8d6f-858b34d1b15d
Treloar, Ben N.
19de1eb9-fe5b-4ade-ad9a-5590a3f79fb5
Knighton, Richard C.
5a63128e-0ebd-466a-b327-3aee6e85a76d
Wills, Martin
4529569b-d977-463d-a99f-fccec46e21a0
Soni, Rina, Jolley, Katherine E., Gosiewska, Silvia, Clarkson, Guy J., Fang, Zhijia, Hall, Thomas H., Treloar, Ben N., Knighton, Richard C. and Wills, Martin
(2018)
Synthesis of enantiomerically pure and racemic benzyl-tethered Ru(II)/TsDPEN complexes by direct arene substitution: further complexes and applications.
Organometallics, 37 (1), .
(doi:10.1021/acs.organomet.7b00731).
Abstract
The use of a direct arene-exchange method for the synthesis of benzyl-tethered arene/Ru/TsDPEN complexes for use in asymmetric transfer hydrogenation is reported. A series of complexes tethered through a three-carbon linear chain was also prepared. The arene-exchange approach significantly simplifies the synthetic approach to this class of catalyst and permits the ready formation of modified analogues. The approach also provides a route to racemic catalysts for use in general reductions with either hydrogen or transfer hydrogenation.
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e-pub ahead of print date: 20 December 2017
Published date: 8 January 2018
Identifiers
Local EPrints ID: 482141
URI: http://eprints.soton.ac.uk/id/eprint/482141
ISSN: 0276-7333
PURE UUID: 9b9ca1b6-555a-449d-959e-d2d29d92147e
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Date deposited: 20 Sep 2023 16:35
Last modified: 18 Mar 2024 04:15
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Author:
Rina Soni
Author:
Katherine E. Jolley
Author:
Silvia Gosiewska
Author:
Guy J. Clarkson
Author:
Zhijia Fang
Author:
Thomas H. Hall
Author:
Ben N. Treloar
Author:
Richard C. Knighton
Author:
Martin Wills
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