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A silver-free system for the direct C-H auration of arenes and heteroarenes from gold chloride complexes

A silver-free system for the direct C-H auration of arenes and heteroarenes from gold chloride complexes
A silver-free system for the direct C-H auration of arenes and heteroarenes from gold chloride complexes

A new methodology for the direct C-H auration of electron-deficient arenes and heteroarenes with simple bases and readily available [Au(PR3)Cl] complexes is described. This system allows the preparation of a wide scope of aryl-Au(i) compounds without the need for using Ag(i) additives or preparing and isolating basic Au(i) hydroxide complexes.

2044-4753
2892-2897
Ahlsten, Nanna
15b4a02d-d70a-44b0-b0fc-3ebb15566ed1
Perry, Gregory J.P.
766e7fc8-abf3-4d1e-9949-c1b3439a2185
Cambeiro, Xacobe C.
7ffebb93-bb0a-4dd6-a079-3aeabb18f082
Boorman, Tanya C.
cce1e418-6a5d-4827-989d-39d0f5ed37ea
Larrosa, Igor
6ab25161-9d87-4f15-8559-0c0e59810989
Ahlsten, Nanna
15b4a02d-d70a-44b0-b0fc-3ebb15566ed1
Perry, Gregory J.P.
766e7fc8-abf3-4d1e-9949-c1b3439a2185
Cambeiro, Xacobe C.
7ffebb93-bb0a-4dd6-a079-3aeabb18f082
Boorman, Tanya C.
cce1e418-6a5d-4827-989d-39d0f5ed37ea
Larrosa, Igor
6ab25161-9d87-4f15-8559-0c0e59810989

Ahlsten, Nanna, Perry, Gregory J.P., Cambeiro, Xacobe C., Boorman, Tanya C. and Larrosa, Igor (2013) A silver-free system for the direct C-H auration of arenes and heteroarenes from gold chloride complexes. Catalysis Science and Technology, 3 (11), 2892-2897. (doi:10.1039/c3cy00240c).

Record type: Article

Abstract

A new methodology for the direct C-H auration of electron-deficient arenes and heteroarenes with simple bases and readily available [Au(PR3)Cl] complexes is described. This system allows the preparation of a wide scope of aryl-Au(i) compounds without the need for using Ag(i) additives or preparing and isolating basic Au(i) hydroxide complexes.

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Accepted/In Press date: 13 June 2013
e-pub ahead of print date: 14 June 2013

Identifiers

Local EPrints ID: 483339
URI: http://eprints.soton.ac.uk/id/eprint/483339
ISSN: 2044-4753
PURE UUID: 3ebe8015-3849-4ba1-b310-a3b5dde71387
ORCID for Gregory J.P. Perry: ORCID iD orcid.org/0000-0001-8173-3369

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Date deposited: 30 Oct 2023 06:29
Last modified: 17 Mar 2024 04:19

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Contributors

Author: Nanna Ahlsten
Author: Gregory J.P. Perry ORCID iD
Author: Xacobe C. Cambeiro
Author: Tanya C. Boorman
Author: Igor Larrosa

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