A silver-free system for the direct C-H auration of arenes and heteroarenes from gold chloride complexes
A silver-free system for the direct C-H auration of arenes and heteroarenes from gold chloride complexes
A new methodology for the direct C-H auration of electron-deficient arenes and heteroarenes with simple bases and readily available [Au(PR3)Cl] complexes is described. This system allows the preparation of a wide scope of aryl-Au(i) compounds without the need for using Ag(i) additives or preparing and isolating basic Au(i) hydroxide complexes.
2892-2897
Ahlsten, Nanna
15b4a02d-d70a-44b0-b0fc-3ebb15566ed1
Perry, Gregory J.P.
766e7fc8-abf3-4d1e-9949-c1b3439a2185
Cambeiro, Xacobe C.
7ffebb93-bb0a-4dd6-a079-3aeabb18f082
Boorman, Tanya C.
cce1e418-6a5d-4827-989d-39d0f5ed37ea
Larrosa, Igor
6ab25161-9d87-4f15-8559-0c0e59810989
Ahlsten, Nanna
15b4a02d-d70a-44b0-b0fc-3ebb15566ed1
Perry, Gregory J.P.
766e7fc8-abf3-4d1e-9949-c1b3439a2185
Cambeiro, Xacobe C.
7ffebb93-bb0a-4dd6-a079-3aeabb18f082
Boorman, Tanya C.
cce1e418-6a5d-4827-989d-39d0f5ed37ea
Larrosa, Igor
6ab25161-9d87-4f15-8559-0c0e59810989
Ahlsten, Nanna, Perry, Gregory J.P., Cambeiro, Xacobe C., Boorman, Tanya C. and Larrosa, Igor
(2013)
A silver-free system for the direct C-H auration of arenes and heteroarenes from gold chloride complexes.
Catalysis Science and Technology, 3 (11), .
(doi:10.1039/c3cy00240c).
Abstract
A new methodology for the direct C-H auration of electron-deficient arenes and heteroarenes with simple bases and readily available [Au(PR3)Cl] complexes is described. This system allows the preparation of a wide scope of aryl-Au(i) compounds without the need for using Ag(i) additives or preparing and isolating basic Au(i) hydroxide complexes.
Text
c3cy00240c
- Version of Record
More information
Accepted/In Press date: 13 June 2013
e-pub ahead of print date: 14 June 2013
Identifiers
Local EPrints ID: 483339
URI: http://eprints.soton.ac.uk/id/eprint/483339
ISSN: 2044-4753
PURE UUID: 3ebe8015-3849-4ba1-b310-a3b5dde71387
Catalogue record
Date deposited: 30 Oct 2023 06:29
Last modified: 17 Mar 2024 04:19
Export record
Altmetrics
Contributors
Author:
Nanna Ahlsten
Author:
Gregory J.P. Perry
Author:
Xacobe C. Cambeiro
Author:
Tanya C. Boorman
Author:
Igor Larrosa
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics