A comparison of different approaches for the analysis of 36Cl in graphite samples
A comparison of different approaches for the analysis of 36Cl in graphite samples
This study compares different approaches for the quantification of the massic activity of 36Cl in graphite samples. All approaches consisted of a combustion step in combination with a trapping solution to collect the volatile elements. Two different resins were used to separate 36Cl from the matrix (CL resin and PS resin). Liquid scintillation counting (LSC), scintillation counting (SC) and tandem inductively coupled plasma mass spectrometry (ICP-MS/MS) were used to quantify 36Cl activity. The chemical yield in all approaches was determined by means of ion chromatography (IC). In addition, the methods were applied to a real activated graphite sample.
Cl, ICP-MS/MS, LSC, Plastic scintillator, Pyrolysis
Llopart-Babot, I.
52008376-da48-4eea-a860-b3235251116c
Vasile, M.
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Dobney, A.
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Russell, B.
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Kolmogorova, S.
54273dea-98d2-46fe-9b24-bfee67009106
Boden, S.
4f368a3f-e09a-4e45-8fb8-822c1a31b0af
Bruggemann, M.
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Leermakers, M.
8812ea83-a2cc-48c1-84c0-f45b1a16c7db
Qiao, J.
352d2763-14ef-44cc-afe7-7f2b0e164346
de Souza, V.
40597599-d527-449d-b649-730da66bd2c4
Tarancon, A.
d07ba47e-e4b8-4993-b380-e0063a85ca34
Bagán, H.
f3424bb0-a589-4011-803f-249de5dad4a5
Warwick, Phillip
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December 2023
Llopart-Babot, I.
52008376-da48-4eea-a860-b3235251116c
Vasile, M.
671ef6f1-2a30-42e6-b7e1-fc9de9521294
Dobney, A.
9239995c-b8a1-47db-9173-5f7378965760
Russell, B.
4d17378f-7a4a-49ea-8a70-1249bab61cf2
Kolmogorova, S.
54273dea-98d2-46fe-9b24-bfee67009106
Boden, S.
4f368a3f-e09a-4e45-8fb8-822c1a31b0af
Bruggemann, M.
6cce6101-c092-4ec7-8ffe-6648c8e8eb62
Leermakers, M.
8812ea83-a2cc-48c1-84c0-f45b1a16c7db
Qiao, J.
352d2763-14ef-44cc-afe7-7f2b0e164346
de Souza, V.
40597599-d527-449d-b649-730da66bd2c4
Tarancon, A.
d07ba47e-e4b8-4993-b380-e0063a85ca34
Bagán, H.
f3424bb0-a589-4011-803f-249de5dad4a5
Warwick, Phillip
f2675d83-eee2-40c5-b53d-fbe437f401ef
Llopart-Babot, I., Vasile, M., Dobney, A., Russell, B., Kolmogorova, S., Boden, S., Bruggemann, M., Leermakers, M., Qiao, J., de Souza, V., Tarancon, A., Bagán, H. and Warwick, Phillip
(2023)
A comparison of different approaches for the analysis of 36Cl in graphite samples.
Applied Radiation and Isotopes, 202, [111046].
(doi:10.1016/j.apradiso.2023.111046).
Abstract
This study compares different approaches for the quantification of the massic activity of 36Cl in graphite samples. All approaches consisted of a combustion step in combination with a trapping solution to collect the volatile elements. Two different resins were used to separate 36Cl from the matrix (CL resin and PS resin). Liquid scintillation counting (LSC), scintillation counting (SC) and tandem inductively coupled plasma mass spectrometry (ICP-MS/MS) were used to quantify 36Cl activity. The chemical yield in all approaches was determined by means of ion chromatography (IC). In addition, the methods were applied to a real activated graphite sample.
Text
Final(B) Llopart Babot et al. 2023
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Restricted to Repository staff only until 29 September 2025.
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More information
Accepted/In Press date: 25 September 2023
e-pub ahead of print date: 26 September 2023
Published date: December 2023
Additional Information:
Funding Information:
Inés Llopart-Babot would like to thank ENGIE for sponsoring this project. Inés Llopart-Babot would also like to thank to the teams of the LSC and gamma-ray spectrometry laboratories at SCK CEN for their support.
Publisher Copyright:
© 2023
Keywords:
Cl, ICP-MS/MS, LSC, Plastic scintillator, Pyrolysis
Identifiers
Local EPrints ID: 483377
URI: http://eprints.soton.ac.uk/id/eprint/483377
ISSN: 0969-8043
PURE UUID: e069d9cc-c721-4665-9d36-33c688e86746
Catalogue record
Date deposited: 30 Oct 2023 12:19
Last modified: 18 Mar 2024 02:41
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Contributors
Author:
I. Llopart-Babot
Author:
M. Vasile
Author:
A. Dobney
Author:
B. Russell
Author:
S. Kolmogorova
Author:
S. Boden
Author:
M. Bruggemann
Author:
M. Leermakers
Author:
J. Qiao
Author:
V. de Souza
Author:
A. Tarancon
Author:
H. Bagán
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