Thioalkylated tetraethylene glycol: a new ligand for water soluble monolayer protected gold clusters
Thioalkylated tetraethylene glycol: a new ligand for water soluble monolayer protected gold clusters
 
  Ligand-stabilised, water-soluble gold nanoparticles of two different size ranges (2–4 and 5–8 nm) are readily prepared using monohydroxy (1-mercaptoundec-11-yl) tetraethylene glycol as a novel capping agent. These nanoparticles are as stable as alkylthiol-capped monolayer protected clusters (MPCs) and do not aggregate from aqueous solution under a wide range of stringent conditions. It is expected that this new material will be useful for a number of bio-analytical applications.
  water-soluble nanoparticles, gold, peg
  
  
  2294-2295
  
    
      Kanaras, A.G.
      
        667ecfdc-7647-4bd8-be03-a47bf32504c7
      
     
  
    
      Kamounah, F.S.
      
        7393c397-4e03-431d-9295-cb7226189bbf
      
     
  
    
      Schaumburg, K.
      
        6a6f0f2f-0ee2-4866-9cfe-ceb5a4f1fffd
      
     
  
    
      Kiely, C.J.
      
        2112322a-0af6-4934-8e88-7c16c61ffdce
      
     
  
    
      Brust, M.
      
        9b9be72b-3ccb-43d0-9d86-723ad680402b
      
     
  
  
   
  
  
    
      2002
    
    
  
  
    
      Kanaras, A.G.
      
        667ecfdc-7647-4bd8-be03-a47bf32504c7
      
     
  
    
      Kamounah, F.S.
      
        7393c397-4e03-431d-9295-cb7226189bbf
      
     
  
    
      Schaumburg, K.
      
        6a6f0f2f-0ee2-4866-9cfe-ceb5a4f1fffd
      
     
  
    
      Kiely, C.J.
      
        2112322a-0af6-4934-8e88-7c16c61ffdce
      
     
  
    
      Brust, M.
      
        9b9be72b-3ccb-43d0-9d86-723ad680402b
      
     
  
       
    
 
  
    
      
  
  
  
  
  
  
    Kanaras, A.G., Kamounah, F.S., Schaumburg, K., Kiely, C.J. and Brust, M.
  
  
  
  
   
    (2002)
  
  
    
    Thioalkylated tetraethylene glycol: a new ligand for water soluble monolayer protected gold clusters.
  
  
  
  
    Chemical Communications, Oct 21 (20), .
  
   (doi:10.1039/b207838b). 
  
  
   
  
  
  
  
  
   
  
    
      
        
          Abstract
          Ligand-stabilised, water-soluble gold nanoparticles of two different size ranges (2–4 and 5–8 nm) are readily prepared using monohydroxy (1-mercaptoundec-11-yl) tetraethylene glycol as a novel capping agent. These nanoparticles are as stable as alkylthiol-capped monolayer protected clusters (MPCs) and do not aggregate from aqueous solution under a wide range of stringent conditions. It is expected that this new material will be useful for a number of bio-analytical applications.
        
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      Published date: 2002
 
    
  
  
    
  
    
  
    
  
    
  
    
     
    
  
    
     
        Keywords:
        water-soluble nanoparticles, gold, peg
      
    
  
    
  
    
  
  
  
    
  
  
        Identifiers
        Local EPrints ID: 48387
        URI: http://eprints.soton.ac.uk/id/eprint/48387
        
          
        
        
        
          ISSN: 1359-7345
        
        
          PURE UUID: dd0f4b3b-f4ca-4557-9e0c-a177ce9c1fc7
        
  
    
        
          
            
              
            
          
        
    
        
          
        
    
        
          
        
    
        
          
        
    
        
          
        
    
  
  Catalogue record
  Date deposited: 19 Sep 2007
  Last modified: 16 Mar 2024 03:56
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      Contributors
      
        
      
          
          Author:
          
            
            
              F.S. Kamounah
            
          
        
      
          
          Author:
          
            
            
              K. Schaumburg
            
          
        
      
          
          Author:
          
            
            
              C.J. Kiely
            
          
        
      
          
          Author:
          
            
            
              M. Brust
            
          
        
      
      
      
    
  
   
  
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