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Synthesis and characterization of UV organic light-emitting electrochemical cells (OLECs) using phenanthrene fluorene derivatives for flexible applications

Synthesis and characterization of UV organic light-emitting electrochemical cells (OLECs) using phenanthrene fluorene derivatives for flexible applications
Synthesis and characterization of UV organic light-emitting electrochemical cells (OLECs) using phenanthrene fluorene derivatives for flexible applications

This paper details how two new small molecules, based on phenanthrene, were developed, and tailored for light-emitting device applications. An account is provided of both the compound synthesis and the methodologies employed in device fabrication. The ink formulation was improved by the use of triflate counterions. Standard bottom emitting devices were constructed on ITO glass along with top emitting devices on a sputter coated silver on glass substrate. Both structures exhibit UV emissions from the synthesized molecules. Successful EL emission within the UV spectrum range has been achieved by spray coating these active molecules onto glass slides. The optimized solution-processed devices produce UV emission using a semi-transparent silver nanowire top electrode. This results in electroluminescence (EL) peaking at 398 nm, with a maximum EL emission intensity of 20.5 μW/cm 2.

OLECs, Organic emitting molecules, Organic light-emitting electrochemical cells, Printed electronics, UV emission, UV emitting molecules
1566-1199
Arumugam, Sasikumar
bda5c9f3-c979-4129-92a3-eaa50d778f4c
Li, Yi
bb52306c-5a20-4bac-b1e3-c2c6a8c6daa2
Pearce, James E.
c8389bad-182d-4ac6-8af0-52fb40b9bb95
Court, Katie L.
076ff46f-bc11-4103-9b0f-88ac5c52b17c
Jackman, Edward H.
cb6d380d-8128-4786-906b-4f4de74eea68
Ward, Oliver J.
80fe56a9-50bc-4d8d-8879-8b43b1d0468d
Tudor, John
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Harrowven, David C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Beeby, Steve P.
ba565001-2812-4300-89f1-fe5a437ecb0d
Arumugam, Sasikumar
bda5c9f3-c979-4129-92a3-eaa50d778f4c
Li, Yi
bb52306c-5a20-4bac-b1e3-c2c6a8c6daa2
Pearce, James E.
c8389bad-182d-4ac6-8af0-52fb40b9bb95
Court, Katie L.
076ff46f-bc11-4103-9b0f-88ac5c52b17c
Jackman, Edward H.
cb6d380d-8128-4786-906b-4f4de74eea68
Ward, Oliver J.
80fe56a9-50bc-4d8d-8879-8b43b1d0468d
Tudor, John
46eea408-2246-4aa0-8b44-86169ed601ff
Harrowven, David C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Beeby, Steve P.
ba565001-2812-4300-89f1-fe5a437ecb0d

Arumugam, Sasikumar, Li, Yi, Pearce, James E., Court, Katie L., Jackman, Edward H., Ward, Oliver J., Tudor, John, Harrowven, David C. and Beeby, Steve P. (2024) Synthesis and characterization of UV organic light-emitting electrochemical cells (OLECs) using phenanthrene fluorene derivatives for flexible applications. Organic Electronics, 130, [107064]. (doi:10.1016/j.orgel.2024.107064).

Record type: Article

Abstract

This paper details how two new small molecules, based on phenanthrene, were developed, and tailored for light-emitting device applications. An account is provided of both the compound synthesis and the methodologies employed in device fabrication. The ink formulation was improved by the use of triflate counterions. Standard bottom emitting devices were constructed on ITO glass along with top emitting devices on a sputter coated silver on glass substrate. Both structures exhibit UV emissions from the synthesized molecules. Successful EL emission within the UV spectrum range has been achieved by spray coating these active molecules onto glass slides. The optimized solution-processed devices produce UV emission using a semi-transparent silver nanowire top electrode. This results in electroluminescence (EL) peaking at 398 nm, with a maximum EL emission intensity of 20.5 μW/cm 2.

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More information

Accepted/In Press date: 7 May 2024
e-pub ahead of print date: 8 May 2024
Published date: 10 May 2024
Keywords: OLECs, Organic emitting molecules, Organic light-emitting electrochemical cells, Printed electronics, UV emission, UV emitting molecules

Identifiers

Local EPrints ID: 490618
URI: http://eprints.soton.ac.uk/id/eprint/490618
ISSN: 1566-1199
PURE UUID: e56f3d4d-8cd1-4813-9c3b-e15b1923ca21
ORCID for Sasikumar Arumugam: ORCID iD orcid.org/0000-0002-7783-1799
ORCID for James E. Pearce: ORCID iD orcid.org/0000-0002-8401-2417
ORCID for John Tudor: ORCID iD orcid.org/0000-0003-1179-9455
ORCID for David C. Harrowven: ORCID iD orcid.org/0000-0001-6730-3573
ORCID for Steve P. Beeby: ORCID iD orcid.org/0000-0002-0800-1759

Catalogue record

Date deposited: 31 May 2024 16:43
Last modified: 06 Jun 2024 01:34

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Contributors

Author: Sasikumar Arumugam ORCID iD
Author: Yi Li
Author: James E. Pearce ORCID iD
Author: Katie L. Court
Author: Edward H. Jackman
Author: Oliver J. Ward
Author: John Tudor ORCID iD
Author: Steve P. Beeby ORCID iD

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