Synthesis and characterization of UV organic light-emitting electrochemical cells (OLECs) using phenanthrene fluorene derivatives for flexible applications
Synthesis and characterization of UV organic light-emitting electrochemical cells (OLECs) using phenanthrene fluorene derivatives for flexible applications
This paper details how two new small molecules, based on phenanthrene, were developed, and tailored for light-emitting device applications. An account is provided of both the compound synthesis and the methodologies employed in device fabrication. The ink formulation was improved by the use of triflate counterions. Standard bottom emitting devices were constructed on ITO glass along with top emitting devices on a sputter coated silver on glass substrate. Both structures exhibit UV emissions from the synthesized molecules. Successful EL emission within the UV spectrum range has been achieved by spray coating these active molecules onto glass slides. The optimized solution-processed devices produce UV emission using a semi-transparent silver nanowire top electrode. This results in electroluminescence (EL) peaking at 398 nm, with a maximum EL emission intensity of 20.5 μW/cm
2.
OLECs, Organic emitting molecules, Organic light-emitting electrochemical cells, Printed electronics, UV emission, UV emitting molecules
Arumugam, Sasikumar
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Li, Yi
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Pearce, James E.
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Court, Katie L.
076ff46f-bc11-4103-9b0f-88ac5c52b17c
Jackman, Edward H.
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Ward, Oliver J.
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Tudor, John
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Harrowven, David C.
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Beeby, Steve P.
ba565001-2812-4300-89f1-fe5a437ecb0d
10 May 2024
Arumugam, Sasikumar
bda5c9f3-c979-4129-92a3-eaa50d778f4c
Li, Yi
bb52306c-5a20-4bac-b1e3-c2c6a8c6daa2
Pearce, James E.
c8389bad-182d-4ac6-8af0-52fb40b9bb95
Court, Katie L.
076ff46f-bc11-4103-9b0f-88ac5c52b17c
Jackman, Edward H.
cb6d380d-8128-4786-906b-4f4de74eea68
Ward, Oliver J.
80fe56a9-50bc-4d8d-8879-8b43b1d0468d
Tudor, John
46eea408-2246-4aa0-8b44-86169ed601ff
Harrowven, David C.
bddcfab6-dbde-49df-aec2-42abbcf5d10b
Beeby, Steve P.
ba565001-2812-4300-89f1-fe5a437ecb0d
Arumugam, Sasikumar, Li, Yi, Pearce, James E., Court, Katie L., Jackman, Edward H., Ward, Oliver J., Tudor, John, Harrowven, David C. and Beeby, Steve P.
(2024)
Synthesis and characterization of UV organic light-emitting electrochemical cells (OLECs) using phenanthrene fluorene derivatives for flexible applications.
Organic Electronics, 130, [107064].
(doi:10.1016/j.orgel.2024.107064).
Abstract
This paper details how two new small molecules, based on phenanthrene, were developed, and tailored for light-emitting device applications. An account is provided of both the compound synthesis and the methodologies employed in device fabrication. The ink formulation was improved by the use of triflate counterions. Standard bottom emitting devices were constructed on ITO glass along with top emitting devices on a sputter coated silver on glass substrate. Both structures exhibit UV emissions from the synthesized molecules. Successful EL emission within the UV spectrum range has been achieved by spray coating these active molecules onto glass slides. The optimized solution-processed devices produce UV emission using a semi-transparent silver nanowire top electrode. This results in electroluminescence (EL) peaking at 398 nm, with a maximum EL emission intensity of 20.5 μW/cm
2.
Text
1-s2.0-S1566119924000752-main
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More information
Accepted/In Press date: 7 May 2024
e-pub ahead of print date: 8 May 2024
Published date: 10 May 2024
Keywords:
OLECs, Organic emitting molecules, Organic light-emitting electrochemical cells, Printed electronics, UV emission, UV emitting molecules
Identifiers
Local EPrints ID: 490618
URI: http://eprints.soton.ac.uk/id/eprint/490618
ISSN: 1566-1199
PURE UUID: e56f3d4d-8cd1-4813-9c3b-e15b1923ca21
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Date deposited: 31 May 2024 16:43
Last modified: 06 Jun 2024 01:34
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Contributors
Author:
Sasikumar Arumugam
Author:
Yi Li
Author:
James E. Pearce
Author:
Katie L. Court
Author:
Edward H. Jackman
Author:
Oliver J. Ward
Author:
John Tudor
Author:
Steve P. Beeby
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