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4D multimaterial printing of soft actuators with spatial and temporal control

4D multimaterial printing of soft actuators with spatial and temporal control
4D multimaterial printing of soft actuators with spatial and temporal control

Soft actuators (SAs) are devices which can interact with delicate objects in a manner not achievable with traditional robotics. While it is possible to design a SA whose actuation is triggered via an external stimulus, the use of a single stimulus creates challenges in the spatial and temporal control of the actuation. Herein, a 4D printed multimaterial soft actuator design (MMSA) whose actuation is only initiated by a combination of triggers (i.e., pH and temperature) is presented. Using 3D printing, a multilayered soft actuator with a hydrophilic pH-sensitive layer, and a hydrophobic magnetic and temperature-responsive shape-memory polymer layer, is designed. The hydrogel responds to environmental pH conditions by swelling or shrinking, while the shape-memory polymer can resist the shape deformation of the hydrogel until triggered by temperature or light. The combination of these stimuli-responsive layers allows for a high level of spatiotemporal control of the actuation. The utility of the 4D MMSA is demonstrated via a series of cargo capture and release experiments, validating its ability to demonstrate active spatiotemporal control. The MMSA concept provides a promising research direction to develop multifunctional soft devices with potential applications in biomedical engineering and environmental engineering.

4D multimaterial printing, pH-responsive hydrogel, photothermal effect, shape-memory polymer, soft actuator, spatial and temporal control, thiol-ene reaction
1521-4095
Zhou, Kun
2bb82231-b6ad-4b96-9b3a-ff3c305436b1
Sun, Rujie
e3dad16d-6c79-4972-8378-edca28a3babd
Wojciechowski, Jonathan P.
7c275478-97aa-45f0-9e92-11443e4cf030
Wang, Richard
bc5ae760-6b13-4a5a-b674-63177a98842f
Yeow, Jonathan
fc76150d-a53a-482f-9fea-278eab082e06
Zuo, Yuyang
fc331884-9986-45fe-a64d-8de991aa6ab5
Song, Xin
a30b4e40-5d47-4e08-bf56-4d8952906f2c
Wang, Chunliang
373f2bd0-9486-4100-87f5-4ad23a0c58d5
Shao, Yue
fa9485dd-ac00-4a01-9d05-982fd2551d80
Stevens, Molly M.
2af17549-764e-4c18-a316-f7dc790398e0
Zhou, Kun
2bb82231-b6ad-4b96-9b3a-ff3c305436b1
Sun, Rujie
e3dad16d-6c79-4972-8378-edca28a3babd
Wojciechowski, Jonathan P.
7c275478-97aa-45f0-9e92-11443e4cf030
Wang, Richard
bc5ae760-6b13-4a5a-b674-63177a98842f
Yeow, Jonathan
fc76150d-a53a-482f-9fea-278eab082e06
Zuo, Yuyang
fc331884-9986-45fe-a64d-8de991aa6ab5
Song, Xin
a30b4e40-5d47-4e08-bf56-4d8952906f2c
Wang, Chunliang
373f2bd0-9486-4100-87f5-4ad23a0c58d5
Shao, Yue
fa9485dd-ac00-4a01-9d05-982fd2551d80
Stevens, Molly M.
2af17549-764e-4c18-a316-f7dc790398e0

Zhou, Kun, Sun, Rujie, Wojciechowski, Jonathan P., Wang, Richard, Yeow, Jonathan, Zuo, Yuyang, Song, Xin, Wang, Chunliang, Shao, Yue and Stevens, Molly M. (2024) 4D multimaterial printing of soft actuators with spatial and temporal control. Advanced Materials, 36 (19), [2312135]. (doi:10.1002/adma.202312135).

Record type: Article

Abstract

Soft actuators (SAs) are devices which can interact with delicate objects in a manner not achievable with traditional robotics. While it is possible to design a SA whose actuation is triggered via an external stimulus, the use of a single stimulus creates challenges in the spatial and temporal control of the actuation. Herein, a 4D printed multimaterial soft actuator design (MMSA) whose actuation is only initiated by a combination of triggers (i.e., pH and temperature) is presented. Using 3D printing, a multilayered soft actuator with a hydrophilic pH-sensitive layer, and a hydrophobic magnetic and temperature-responsive shape-memory polymer layer, is designed. The hydrogel responds to environmental pH conditions by swelling or shrinking, while the shape-memory polymer can resist the shape deformation of the hydrogel until triggered by temperature or light. The combination of these stimuli-responsive layers allows for a high level of spatiotemporal control of the actuation. The utility of the 4D MMSA is demonstrated via a series of cargo capture and release experiments, validating its ability to demonstrate active spatiotemporal control. The MMSA concept provides a promising research direction to develop multifunctional soft devices with potential applications in biomedical engineering and environmental engineering.

Text
Advanced Materials - 2024 - Zhou - 4D Multimaterial Printing of Soft Actuators with Spatial and Temporal Control - Version of Record
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e-pub ahead of print date: 30 January 2024
Published date: 9 May 2024
Keywords: 4D multimaterial printing, pH-responsive hydrogel, photothermal effect, shape-memory polymer, soft actuator, spatial and temporal control, thiol-ene reaction

Identifiers

Local EPrints ID: 491095
URI: http://eprints.soton.ac.uk/id/eprint/491095
ISSN: 1521-4095
PURE UUID: 62795e7d-3e3e-4ce0-a1b0-526b26dbf6b1

Catalogue record

Date deposited: 11 Jun 2024 23:57
Last modified: 11 Jun 2024 23:57

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Contributors

Author: Kun Zhou
Author: Rujie Sun
Author: Jonathan P. Wojciechowski
Author: Richard Wang
Author: Jonathan Yeow
Author: Yuyang Zuo
Author: Xin Song
Author: Chunliang Wang
Author: Yue Shao
Author: Molly M. Stevens

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