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Pourbaix diagrams as a simple route to first principles corrosion simulation

Pourbaix diagrams as a simple route to first principles corrosion simulation
Pourbaix diagrams as a simple route to first principles corrosion simulation
Simulation of corrosion reactions has become an important tool in the analysis of novel materials for corrosion resistant materials and applications. A number of analytical, boundary element and finite element methods currently exist in the literature, which use experimental corrosion parameters as model inputs for the extraction of simulated polarization curves, oxide growth rates, and other corrosion behaviors. Here, we propose the combination of finite element simulation with thermodynamic data from Pourbaix diagrams to allow for the simulation of metal corrosion, where individual corrosion reactions can be monitored at the metal surface.
0013-4651
Perry, S.C.
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Gateman, S.M.
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Stephens, L.I.
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Lacasse, R.
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Schulz, R.
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Mauzeroll, J.
af84f034-1e52-4419-a1c2-ce7116db5b07
Perry, S.C.
8e204d86-4a9c-4a5d-9932-cf470174648e
Gateman, S.M.
55ceb3a2-dd5d-48c2-b3a2-6ac8e86f2790
Stephens, L.I.
d6218c34-25bd-4312-b2bd-f115d2af1d50
Lacasse, R.
634a206f-22a0-4513-b91f-42273124122b
Schulz, R.
20a694bd-b263-4f5e-98ba-5150c51b8c41
Mauzeroll, J.
af84f034-1e52-4419-a1c2-ce7116db5b07

Perry, S.C., Gateman, S.M., Stephens, L.I., Lacasse, R., Schulz, R. and Mauzeroll, J. (2019) Pourbaix diagrams as a simple route to first principles corrosion simulation. Journal of the Electrochemical Society, 166 (11), [C3186]. (doi:10.1149/2.0111911jes).

Record type: Article

Abstract

Simulation of corrosion reactions has become an important tool in the analysis of novel materials for corrosion resistant materials and applications. A number of analytical, boundary element and finite element methods currently exist in the literature, which use experimental corrosion parameters as model inputs for the extraction of simulated polarization curves, oxide growth rates, and other corrosion behaviors. Here, we propose the combination of finite element simulation with thermodynamic data from Pourbaix diagrams to allow for the simulation of metal corrosion, where individual corrosion reactions can be monitored at the metal surface.

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Perry_2019_J._Electrochem._Soc._166_C3186 - Version of Record
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Submitted date: 21 January 2019
Published date: 2 May 2019

Identifiers

Local EPrints ID: 491282
URI: http://eprints.soton.ac.uk/id/eprint/491282
ISSN: 0013-4651
PURE UUID: cc07c593-4f3e-4005-8815-0eaba503faa3
ORCID for S.C. Perry: ORCID iD orcid.org/0000-0002-6263-6114

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Date deposited: 18 Jun 2024 16:58
Last modified: 19 Jun 2024 01:55

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Contributors

Author: S.C. Perry ORCID iD
Author: S.M. Gateman
Author: L.I. Stephens
Author: R. Lacasse
Author: R. Schulz
Author: J. Mauzeroll

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