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UV-visible spectroscopic studies of group 8-10 metal trifluorides

UV-visible spectroscopic studies of group 8-10 metal trifluorides
UV-visible spectroscopic studies of group 8-10 metal trifluorides

Diffuse reflectance UV-visible spectra (2000-200 nm/5000-50 000 cm-1) are reported for FeF3, CoF3, RuF3, RhF3, IrF3 and PdF3. Assignments for the spectra are proposed and compared with literature data on related hexafluoroanions [MF6]n-. The spectrum of PdF3 is consistent with the known mixed-valence PdII[PdIVF6] constitution of this material.

Transition metal, Trifluoride, UV-visible spectra
0022-1139
161-165
Hector, Andrew L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Weller, Mark T.
36a60b56-049f-466c-a1d7-39d6b0d85ff4
Hope, Eric G.
b2554b87-8d1e-4099-947c-0878b04fa5ed
Hector, Andrew L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Weller, Mark T.
36a60b56-049f-466c-a1d7-39d6b0d85ff4
Hope, Eric G.
b2554b87-8d1e-4099-947c-0878b04fa5ed

Hector, Andrew L., Levason, William, Weller, Mark T. and Hope, Eric G. (1997) UV-visible spectroscopic studies of group 8-10 metal trifluorides. Journal of Fluorine Chemistry, 84 (2), 161-165. (doi:10.1016/S0022-1139(97)00053-5).

Record type: Article

Abstract

Diffuse reflectance UV-visible spectra (2000-200 nm/5000-50 000 cm-1) are reported for FeF3, CoF3, RuF3, RhF3, IrF3 and PdF3. Assignments for the spectra are proposed and compared with literature data on related hexafluoroanions [MF6]n-. The spectrum of PdF3 is consistent with the known mixed-valence PdII[PdIVF6] constitution of this material.

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More information

Published date: 1 September 1997
Keywords: Transition metal, Trifluoride, UV-visible spectra

Identifiers

Local EPrints ID: 491413
URI: http://eprints.soton.ac.uk/id/eprint/491413
DOI: doi:10.1016/S0022-1139(97)00053-5
ISSN: 0022-1139
PURE UUID: 0cdb942c-a0ee-41c6-86a6-1891c607fb54
ORCID for Andrew L. Hector: ORCID iD orcid.org/0000-0002-9964-2163
ORCID for William Levason: ORCID iD orcid.org/0000-0003-3540-0971

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Date deposited: 21 Jun 2024 17:08
Last modified: 22 Jun 2024 01:34

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Contributors

Author: Andrew L. Hector ORCID iD
Author: William Levason ORCID iD
Author: Mark T. Weller
Author: Eric G. Hope

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