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High oxidation state alkali-metal late-transition-metal oxides

High oxidation state alkali-metal late-transition-metal oxides
High oxidation state alkali-metal late-transition-metal oxides

Li2NaCu2O4 has been prepared by solid state reaction under high-pressure (250 Atm) oxygen. A structural study, using time-of-flight powder neutron diffraction on a sample made with 7Li, shows a material isostructural with Li3Cu2O4, with sodium occupying the octahedral and lithium the tetrahedral A-cation sites. A 7Li MAS-NMR study of Li3Cu2O4, Li2NaCu2O4 and Li2CuO2 has been used to confirm the Li/Na site ordering.

0272-9172
GG951-GG956
Currie, David B.
5adbfcbf-0804-43b5-9883-d5158dcbf072
Hector, Andrew L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Raekelboom, Emmanuelle A.
e15c3b3b-6b25-46b1-b7d2-40d24a9468cf
Owen, John R.
067986ea-f3f3-4a83-bc87-7387cc5ac85d
Weller, Mark T.
36a60b56-049f-466c-a1d7-39d6b0d85ff4
Currie, David B.
5adbfcbf-0804-43b5-9883-d5158dcbf072
Hector, Andrew L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Raekelboom, Emmanuelle A.
e15c3b3b-6b25-46b1-b7d2-40d24a9468cf
Owen, John R.
067986ea-f3f3-4a83-bc87-7387cc5ac85d
Weller, Mark T.
36a60b56-049f-466c-a1d7-39d6b0d85ff4

Currie, David B., Hector, Andrew L., Raekelboom, Emmanuelle A., Owen, John R. and Weller, Mark T. (2001) High oxidation state alkali-metal late-transition-metal oxides. Materials Research Society Symposium - Proceedings, 658, GG951-GG956, [95]. (doi:10.1557/PROC-658-GG9.5).

Record type: Article

Abstract

Li2NaCu2O4 has been prepared by solid state reaction under high-pressure (250 Atm) oxygen. A structural study, using time-of-flight powder neutron diffraction on a sample made with 7Li, shows a material isostructural with Li3Cu2O4, with sodium occupying the octahedral and lithium the tetrahedral A-cation sites. A 7Li MAS-NMR study of Li3Cu2O4, Li2NaCu2O4 and Li2CuO2 has been used to confirm the Li/Na site ordering.

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Published date: 1 July 2001
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Identifiers

Local EPrints ID: 491738
URI: http://eprints.soton.ac.uk/id/eprint/491738
DOI: doi:10.1557/PROC-658-GG9.5
ISSN: 0272-9172
PURE UUID: 279f177d-c206-479d-a31a-b2776b98e53c
ORCID for Andrew L. Hector: ORCID iD orcid.org/0000-0002-9964-2163
ORCID for John R. Owen: ORCID iD orcid.org/0000-0002-4938-3693

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Date deposited: 03 Jul 2024 16:58
Last modified: 11 Jul 2024 01:37

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Contributors

Author: David B. Currie
Author: Andrew L. Hector ORCID iD
Author: Emmanuelle A. Raekelboom
Author: John R. Owen ORCID iD
Author: Mark T. Weller

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