Cuvette-based electrogenerated chemiluminescence detection system for the assessment of polymerizable ruthenium luminophores
Cuvette-based electrogenerated chemiluminescence detection system for the assessment of polymerizable ruthenium luminophores
Herein, we validate a novel cuvette-based approach to measure electrogenerated chemiluminescence (ECL) by employing the hyphenation of a commercial spectrometer and a potentiostat. The new experimental design provides simultaneous acquisition of electrochemical and ECL data, allowing complementary analysis by both techniques. Preliminary analysis of an organometallic ECL standard, tris(2,2′-bipyridine)ruthenium(II) (Ru(bpy)32+), and tripropylamine (TPA), showed excellent reproducibility both in terms of the electrochemistry and the ECL signal. Equally as important, the acquired electrochemistry and ECL from the Ru(bpy)32+/TPA system served as a baseline for evaluating the ECL response of polymerizable ruthenium luminophores.
176-1743
Danis, Andrew S.
33a0334e-3346-4b85-86c4-3619bad2e8a4
Odette, William L.
d082262e-433a-4b2e-8d69-587d6204a402
Perry, Samuel C.
8e204d86-4a9c-4a5d-9932-cf470174648e
Canesi, Sylvain
9db8392d-9db8-48f8-9c23-66499a886924
Sleiman, Hanadi F.
45bd26d4-0e66-4d5c-ac66-fdb5308a7129
Mauzeroll, Janine
af84f034-1e52-4419-a1c2-ce7116db5b07
23 February 2017
Danis, Andrew S.
33a0334e-3346-4b85-86c4-3619bad2e8a4
Odette, William L.
d082262e-433a-4b2e-8d69-587d6204a402
Perry, Samuel C.
8e204d86-4a9c-4a5d-9932-cf470174648e
Canesi, Sylvain
9db8392d-9db8-48f8-9c23-66499a886924
Sleiman, Hanadi F.
45bd26d4-0e66-4d5c-ac66-fdb5308a7129
Mauzeroll, Janine
af84f034-1e52-4419-a1c2-ce7116db5b07
Danis, Andrew S., Odette, William L., Perry, Samuel C., Canesi, Sylvain, Sleiman, Hanadi F. and Mauzeroll, Janine
(2017)
Cuvette-based electrogenerated chemiluminescence detection system for the assessment of polymerizable ruthenium luminophores.
ChemElectroChem, 4 (7), .
(doi:10.1002/celc.201600879).
Abstract
Herein, we validate a novel cuvette-based approach to measure electrogenerated chemiluminescence (ECL) by employing the hyphenation of a commercial spectrometer and a potentiostat. The new experimental design provides simultaneous acquisition of electrochemical and ECL data, allowing complementary analysis by both techniques. Preliminary analysis of an organometallic ECL standard, tris(2,2′-bipyridine)ruthenium(II) (Ru(bpy)32+), and tripropylamine (TPA), showed excellent reproducibility both in terms of the electrochemistry and the ECL signal. Equally as important, the acquired electrochemistry and ECL from the Ru(bpy)32+/TPA system served as a baseline for evaluating the ECL response of polymerizable ruthenium luminophores.
This record has no associated files available for download.
More information
e-pub ahead of print date: 2 February 2017
Published date: 23 February 2017
Identifiers
Local EPrints ID: 491854
URI: http://eprints.soton.ac.uk/id/eprint/491854
ISSN: 2196-0216
PURE UUID: daf93078-82d2-4744-b96a-4458cc69b6ed
Catalogue record
Date deposited: 04 Jul 2024 17:19
Last modified: 11 Jul 2024 02:01
Export record
Altmetrics
Contributors
Author:
Andrew S. Danis
Author:
William L. Odette
Author:
Samuel C. Perry
Author:
Sylvain Canesi
Author:
Hanadi F. Sleiman
Author:
Janine Mauzeroll
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics