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Method of invariant manifold for chemical kinetics

Method of invariant manifold for chemical kinetics
Method of invariant manifold for chemical kinetics
In this paper, we review the construction of low-dimensional manifolds of reduced description for equations of chemical kinetics from the standpoint of the method of invariant manifold (MIM). The MIM is based on a formulation of the condition of invariance as an equation, and its solution by Newton iterations. A review of existing alternative methods is extended by a thermodynamically consistent version of the method of intrinsic low-dimensional manifolds. A grid-based version of the MIM is developed, and model extensions of low-dimensional dynamics are described. Generalizations to open systems are suggested. The set of methods covered makes it possible to effectively reduce description in chemical kinetics
0009-2509
4751-4768
Gorban, A.N.
3b4ae629-6486-47c8-9d6c-6d89a9985dd5
Karlin, I.V.
3f0e01a2-c4d9-4210-9ef3-47e6c426cc8a
Gorban, A.N.
3b4ae629-6486-47c8-9d6c-6d89a9985dd5
Karlin, I.V.
3f0e01a2-c4d9-4210-9ef3-47e6c426cc8a

Gorban, A.N. and Karlin, I.V. (2003) Method of invariant manifold for chemical kinetics. Chemical Engineering Science, 58 (21), 4751-4768. (doi:10.1016/j.ces.2002.12.001).

Record type: Article

Abstract

In this paper, we review the construction of low-dimensional manifolds of reduced description for equations of chemical kinetics from the standpoint of the method of invariant manifold (MIM). The MIM is based on a formulation of the condition of invariance as an equation, and its solution by Newton iterations. A review of existing alternative methods is extended by a thermodynamically consistent version of the method of intrinsic low-dimensional manifolds. A grid-based version of the MIM is developed, and model extensions of low-dimensional dynamics are described. Generalizations to open systems are suggested. The set of methods covered makes it possible to effectively reduce description in chemical kinetics

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Published date: November 2003

Identifiers

Local EPrints ID: 49190
URI: http://eprints.soton.ac.uk/id/eprint/49190
ISSN: 0009-2509
PURE UUID: 249ba4a9-e889-49b4-a66e-d178506fd712

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Date deposited: 24 Oct 2007
Last modified: 15 Mar 2024 09:53

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Contributors

Author: A.N. Gorban
Author: I.V. Karlin

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