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Improving the strength and surface properties of TNTZ alloy through a combination of high-pressure torsion and laser surface treatment

Improving the strength and surface properties of TNTZ alloy through a combination of high-pressure torsion and laser surface treatment
Improving the strength and surface properties of TNTZ alloy through a combination of high-pressure torsion and laser surface treatment
The Ti–29Nb–13Ta–4.6Zr alloy (TNTZ) is a β-Ti alloy that has a potential for use in biomedical applications as an alternative to the less-compatible Ti64 alloys. Enhancing the strength and the surface finish of TNTZ is essential for biomedical applications. In this research, a combination of high-pressure torsion (HPT) and laser treatment was used to improve the TNTZ properties. The HPT-treated samples showed significantly enhanced mechanical properties when compared with the traditional solution-treated TNTZ. A laser surface treatment immediately forms a hydrophilic surface that transforms into a steady hydrophobic state after 14 days in air and the surface roughness increases with an increase in laser power and a slower scanning rate. The corrosion resistance of TNTZ improves significantly after laser treatment, with the corrosion current dropping from 1×10-8 A to 1.2 ×10-9 A and the corrosion potential peak shifting to a more positive value from -0.349 V to -0.158 V. The friction coefficient after laser treatment decreased from 0.134 to 0.093 and then further reduced to 0.082 after 14 days in air thereby suggesting an enhancement in the tribological properties. Overall, the results show that HPT processing combined with a post-HPT laser treatment is beneficial for enhancing the mechanical properties and the corrosion and wear performance of the TNTZ alloy.
TNTZ alloy, electrochemistry, high-pressure torsion, hydrophobicity, laser surface modification
2693–2704
Lin, Hsuan-Kai
51b9d2d1-713d-46c4-a761-953b1aaebb34
Hsieh, Tsai-Hsuan
4e600908-f87a-483a-9602-422bd3f9cadc
Cheng, Yi-Hong
acd33faf-7ee8-4248-babb-6f3fa2f19b59
Bazarnik, Piotr
d6764d8b-39bb-43eb-a3b1-09043b4575df
Wang, Chuan Ting
80ad9adf-a9df-49ed-934d-fa64505b920d
Huang, Yi
9f4df815-51c1-4ee8-ad63-a92bf997103e
Ye, Jing
402767f1-5e59-433b-9f5e-0d14bac7ccdd
Abdelkader, Amor
2f14b176-9572-449f-b873-665e38afa0a9
Langdon, Terence G.
86e69b4f-e16d-4830-bf8a-5a9c11f0de86
Lin, Hsuan-Kai
51b9d2d1-713d-46c4-a761-953b1aaebb34
Hsieh, Tsai-Hsuan
4e600908-f87a-483a-9602-422bd3f9cadc
Cheng, Yi-Hong
acd33faf-7ee8-4248-babb-6f3fa2f19b59
Bazarnik, Piotr
d6764d8b-39bb-43eb-a3b1-09043b4575df
Wang, Chuan Ting
80ad9adf-a9df-49ed-934d-fa64505b920d
Huang, Yi
9f4df815-51c1-4ee8-ad63-a92bf997103e
Ye, Jing
402767f1-5e59-433b-9f5e-0d14bac7ccdd
Abdelkader, Amor
2f14b176-9572-449f-b873-665e38afa0a9
Langdon, Terence G.
86e69b4f-e16d-4830-bf8a-5a9c11f0de86

Lin, Hsuan-Kai, Hsieh, Tsai-Hsuan, Cheng, Yi-Hong, Bazarnik, Piotr, Wang, Chuan Ting, Huang, Yi, Ye, Jing, Abdelkader, Amor and Langdon, Terence G. (2024) Improving the strength and surface properties of TNTZ alloy through a combination of high-pressure torsion and laser surface treatment. The International Journey of Advanced Manufacturing Technology, 134 (5-6), 2693–2704. (doi:10.1007/s00170-024-14293-1).

Record type: Article

Abstract

The Ti–29Nb–13Ta–4.6Zr alloy (TNTZ) is a β-Ti alloy that has a potential for use in biomedical applications as an alternative to the less-compatible Ti64 alloys. Enhancing the strength and the surface finish of TNTZ is essential for biomedical applications. In this research, a combination of high-pressure torsion (HPT) and laser treatment was used to improve the TNTZ properties. The HPT-treated samples showed significantly enhanced mechanical properties when compared with the traditional solution-treated TNTZ. A laser surface treatment immediately forms a hydrophilic surface that transforms into a steady hydrophobic state after 14 days in air and the surface roughness increases with an increase in laser power and a slower scanning rate. The corrosion resistance of TNTZ improves significantly after laser treatment, with the corrosion current dropping from 1×10-8 A to 1.2 ×10-9 A and the corrosion potential peak shifting to a more positive value from -0.349 V to -0.158 V. The friction coefficient after laser treatment decreased from 0.134 to 0.093 and then further reduced to 0.082 after 14 days in air thereby suggesting an enhancement in the tribological properties. Overall, the results show that HPT processing combined with a post-HPT laser treatment is beneficial for enhancing the mechanical properties and the corrosion and wear performance of the TNTZ alloy.

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LinHK-TNTZ paper accepted
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More information

Accepted/In Press date: 14 August 2024
Published date: 25 August 2024
Keywords: TNTZ alloy, electrochemistry, high-pressure torsion, hydrophobicity, laser surface modification

Identifiers

Local EPrints ID: 493627
URI: http://eprints.soton.ac.uk/id/eprint/493627
PURE UUID: cbf11510-8b8f-450b-bfd4-2c3388035ed9
ORCID for Yi Huang: ORCID iD orcid.org/0000-0001-9259-8123
ORCID for Terence G. Langdon: ORCID iD orcid.org/0000-0003-3541-9250

Catalogue record

Date deposited: 09 Sep 2024 16:55
Last modified: 08 Nov 2024 02:43

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Contributors

Author: Hsuan-Kai Lin
Author: Tsai-Hsuan Hsieh
Author: Yi-Hong Cheng
Author: Piotr Bazarnik
Author: Chuan Ting Wang
Author: Yi Huang ORCID iD
Author: Jing Ye
Author: Amor Abdelkader

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