Thermoplastic starch processed under various manufacturing conditions: thermal and electrical properties

Drakopoulos, Stavros X., Vryonis, Orestis, Špitalský, Zdenko, Peidayesh, Hamed and Lendvai, László (2024) Thermoplastic starch processed under various manufacturing conditions: thermal and electrical properties. Biomacromolecules, 25 (9), 5938-5948. (doi:10.1021/acs.biomac.4c00602).

Abstract

Eco-friendly materials like carbohydrate-based polymers are important for a sustainable future. Starch is particularly promising because of its biodegradability and abundance but its processing to thermoplastic starch requires optimization. Here we developed thermoplastic maize starch materials based on three manufacturing protocols, namely: (1) starch/glycerol manual mixing and extrusion, (2) starch/glycerol manual mixing, extrusion, and kneading, (3) starch/glycerol/water manual mixing and kneading. The physical properties were investigated by differential scanning calorimetry, thermogravimetric analysis, and broadband dielectric spectroscopy. As expected from a partially miscible blend, the dielectric spectra revealed two distinct α-relaxations for the glycerol-rich and the starch-rich phases, respectively. By employing kneading after extrusion, the miscibility between the two phases was found to improve based on thermal and dielectric methods. Moreover, the addition of water during the premixing stage was observed to facilitate phase separation between starch and glycerol, with the α-relaxation dynamics of the latter being comparable to pure glycerol.

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Contributors

Author: Orestis Vryonis

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