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Leaky integrate-and-fire model and short-term synaptic plasticity emulated in a novel bismuth-based diffusive memristor

Leaky integrate-and-fire model and short-term synaptic plasticity emulated in a novel bismuth-based diffusive memristor
Leaky integrate-and-fire model and short-term synaptic plasticity emulated in a novel bismuth-based diffusive memristor

Memristors, being prospective work-horses of future electronics offer various types of memory (volatile and nonvolatile) along with specific computational functionalities. Further development of memristive technologies depends on the availability of suitable materials. These materials should be easily available, stable, and preferably of low toxicity. Commonly used materials are lead halide perovskites, however, they are highly toxic and unstable under ambient conditions. Therefore a novel material is developed on the basis of bismuth iodide. In reaction with butylammonium iodide, it yields a novel compound, butylammonium iodobismuthate (BABI). Here, a diffusive memristor is introduced based on this compound and evaluates its memristive and neuromorphic properties. In contrast to nonvolatile memristors, the BABI memristors exhibit diffusive dynamics, which enable them to store the information only for short periods of time. This property is utilized to mimic the short-term synaptic plasticity described by the leaky integrate-and-fire model of a biological neuron. Combined with high switching uniformity and self-rectifying behavior, these devices show high classification accuracy for MNIST handwritten datasets, paving the way for their application in neuromorphic computing systems.

bismuth iodide, diffusive memristor, neuromorphic computing, resistive switching, synaptic plasticity
2199-160X
Zawal, Piotr
d06a938a-1a47-4427-b54e-82d83bcaffb8
Abdi, Gisya
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Gryl, Marlena
3742d2e4-c060-41eb-bbed-90219338e0f6
Das, Dip
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Sławek, Andrzej
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Gerouville, Emilie A.
7ae5faf3-de93-4951-b9ba-ed98de594cd2
Marciszko-Wiackowska, Marianna
884b1a00-b04c-4150-88ac-767ab4260c9c
Marzec, Mateusz
9abe822f-c6d5-4cde-b73a-32168257d849
Hess, Grzegorz
945e3910-5cde-4be6-9e72-678b14bcfca6
Georgiadou, Dimitra
84977176-3678-4fb3-a3dd-2044a49c853b
Szaciłowsk, Konrad
df05d42b-e7d6-4a58-a8a8-c7280411b344
Zawal, Piotr
d06a938a-1a47-4427-b54e-82d83bcaffb8
Abdi, Gisya
67897942-835f-4e8a-8e74-7366ed0329ec
Gryl, Marlena
3742d2e4-c060-41eb-bbed-90219338e0f6
Das, Dip
278a3e31-2dc5-458f-b33c-dae21b39cd7e
Sławek, Andrzej
43c929e3-db23-4a00-a2c2-6f102321beb9
Gerouville, Emilie A.
7ae5faf3-de93-4951-b9ba-ed98de594cd2
Marciszko-Wiackowska, Marianna
884b1a00-b04c-4150-88ac-767ab4260c9c
Marzec, Mateusz
9abe822f-c6d5-4cde-b73a-32168257d849
Hess, Grzegorz
945e3910-5cde-4be6-9e72-678b14bcfca6
Georgiadou, Dimitra
84977176-3678-4fb3-a3dd-2044a49c853b
Szaciłowsk, Konrad
df05d42b-e7d6-4a58-a8a8-c7280411b344

Zawal, Piotr, Abdi, Gisya, Gryl, Marlena, Das, Dip, Sławek, Andrzej, Gerouville, Emilie A., Marciszko-Wiackowska, Marianna, Marzec, Mateusz, Hess, Grzegorz, Georgiadou, Dimitra and Szaciłowsk, Konrad (2024) Leaky integrate-and-fire model and short-term synaptic plasticity emulated in a novel bismuth-based diffusive memristor. Advanced Electronic Materials, 10 (7), [2300865]. (doi:10.1002/aelm.202300865).

Record type: Article

Abstract

Memristors, being prospective work-horses of future electronics offer various types of memory (volatile and nonvolatile) along with specific computational functionalities. Further development of memristive technologies depends on the availability of suitable materials. These materials should be easily available, stable, and preferably of low toxicity. Commonly used materials are lead halide perovskites, however, they are highly toxic and unstable under ambient conditions. Therefore a novel material is developed on the basis of bismuth iodide. In reaction with butylammonium iodide, it yields a novel compound, butylammonium iodobismuthate (BABI). Here, a diffusive memristor is introduced based on this compound and evaluates its memristive and neuromorphic properties. In contrast to nonvolatile memristors, the BABI memristors exhibit diffusive dynamics, which enable them to store the information only for short periods of time. This property is utilized to mimic the short-term synaptic plasticity described by the leaky integrate-and-fire model of a biological neuron. Combined with high switching uniformity and self-rectifying behavior, these devices show high classification accuracy for MNIST handwritten datasets, paving the way for their application in neuromorphic computing systems.

Text
Adv Elect Materials - 2024 - Zawal - Leaky Integrate‐and‐Fire Model and Short‐Term Synaptic Plasticity Emulated in a Novel - Version of Record
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e-pub ahead of print date: 1 May 2024
Keywords: bismuth iodide, diffusive memristor, neuromorphic computing, resistive switching, synaptic plasticity

Identifiers

Local EPrints ID: 497137
URI: http://eprints.soton.ac.uk/id/eprint/497137
ISSN: 2199-160X
PURE UUID: 31819caa-9e76-4e10-8d52-9d607e4726f6
ORCID for Dimitra Georgiadou: ORCID iD orcid.org/0000-0002-2620-3346

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Date deposited: 14 Jan 2025 17:57
Last modified: 22 Aug 2025 02:28

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Contributors

Author: Piotr Zawal
Author: Gisya Abdi
Author: Marlena Gryl
Author: Dip Das
Author: Andrzej Sławek
Author: Emilie A. Gerouville
Author: Marianna Marciszko-Wiackowska
Author: Mateusz Marzec
Author: Grzegorz Hess
Author: Konrad Szaciłowsk

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