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Corrosion performance of Al-6061 alloy after high-pressure torsion processing

Corrosion performance of Al-6061 alloy after high-pressure torsion processing
Corrosion performance of Al-6061 alloy after high-pressure torsion processing
The corrosion behavior of a commercial Al-6061 alloy was explored in a 3.5 % (wt%) NaCl solution after high-pressure torsion (HPT) processing at room temperature for numbers of revolutions of N = 0, 1/2, 2 and 10 turns. The microstructures revealed by electron backscatter diffraction (EBSD) showed excellent grain refinement from 121 ± 5 to 0.44 ± 0.1 μm after N = 10 turns with a high fraction of high-angle grain boundaries (∼65 %). The results from electrochemical tests demonstrate that HPT processing significantly improves the corrosion resistance and reduces the corrosion rate due to a combination of grain refinement, an increased dislocation density and texture weakening. The corrosion mechanism was not affected by the HPT processing and found to be controlled by charge transfer. The corrosion morphology of the HPT-processed sample taken through N = 10 turns and observed after 14 days of immersion showed a smooth surface except for the presence of some corrosion microcracks around large particles enriched with Zn and Fe elements.
aluminium alloy, corrosion, high-pressure torsion, microstructure, ultrafine grains, Ultrafine grains, Corrosion, High-pressure torsion, Microstructure, Aluminum alloy
1044-5803
Khalfallah, Abdelkader
6a650bab-0b99-4cdb-9d3c-acc6b683adb3
Amzert, Sid Ahmed
990fb86e-888a-4ed2-bb33-3957491e7193
Arbaoui, Fahd
7e1f00ba-ef33-44d9-811f-31dfad986849
Titouche, Nacereddine
ce802fe7-e12e-4a98-a01d-8269699a079a
Selmi, Noureddine
ae916afd-3fa8-4857-ac71-15e884d9c3ae
Bazarnik, Piotr
d6764d8b-39bb-43eb-a3b1-09043b4575df
Azzeddine, Hiba
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Baudin, Thierry
448e215d-c156-4c0a-9a3a-04078a7174b8
Brisset, François
c93ca177-5b75-400d-a9fb-85a567cebec6
Huang, Yi
9f4df815-51c1-4ee8-ad63-a92bf997103e
Langdon, Terence G.
86e69b4f-e16d-4830-bf8a-5a9c11f0de86
Khalfallah, Abdelkader
6a650bab-0b99-4cdb-9d3c-acc6b683adb3
Amzert, Sid Ahmed
990fb86e-888a-4ed2-bb33-3957491e7193
Arbaoui, Fahd
7e1f00ba-ef33-44d9-811f-31dfad986849
Titouche, Nacereddine
ce802fe7-e12e-4a98-a01d-8269699a079a
Selmi, Noureddine
ae916afd-3fa8-4857-ac71-15e884d9c3ae
Bazarnik, Piotr
d6764d8b-39bb-43eb-a3b1-09043b4575df
Azzeddine, Hiba
9d0bbd8e-680c-48d1-b27a-fbdd23cd2228
Baudin, Thierry
448e215d-c156-4c0a-9a3a-04078a7174b8
Brisset, François
c93ca177-5b75-400d-a9fb-85a567cebec6
Huang, Yi
9f4df815-51c1-4ee8-ad63-a92bf997103e
Langdon, Terence G.
86e69b4f-e16d-4830-bf8a-5a9c11f0de86

Khalfallah, Abdelkader, Amzert, Sid Ahmed, Arbaoui, Fahd, Titouche, Nacereddine, Selmi, Noureddine, Bazarnik, Piotr, Azzeddine, Hiba, Baudin, Thierry, Brisset, François, Huang, Yi and Langdon, Terence G. (2025) Corrosion performance of Al-6061 alloy after high-pressure torsion processing. Materials Characterization, 220, [114714]. (doi:10.1016/j.matchar.2025.114714).

Record type: Article

Abstract

The corrosion behavior of a commercial Al-6061 alloy was explored in a 3.5 % (wt%) NaCl solution after high-pressure torsion (HPT) processing at room temperature for numbers of revolutions of N = 0, 1/2, 2 and 10 turns. The microstructures revealed by electron backscatter diffraction (EBSD) showed excellent grain refinement from 121 ± 5 to 0.44 ± 0.1 μm after N = 10 turns with a high fraction of high-angle grain boundaries (∼65 %). The results from electrochemical tests demonstrate that HPT processing significantly improves the corrosion resistance and reduces the corrosion rate due to a combination of grain refinement, an increased dislocation density and texture weakening. The corrosion mechanism was not affected by the HPT processing and found to be controlled by charge transfer. The corrosion morphology of the HPT-processed sample taken through N = 10 turns and observed after 14 days of immersion showed a smooth surface except for the presence of some corrosion microcracks around large particles enriched with Zn and Fe elements.

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Hiba_Mater Characterizations_accepted - Accepted Manuscript
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Accepted/In Press date: 2 January 2025
e-pub ahead of print date: 3 January 2025
Published date: 4 January 2025
Keywords: aluminium alloy, corrosion, high-pressure torsion, microstructure, ultrafine grains, Ultrafine grains, Corrosion, High-pressure torsion, Microstructure, Aluminum alloy

Identifiers

Local EPrints ID: 497573
URI: http://eprints.soton.ac.uk/id/eprint/497573
ISSN: 1044-5803
PURE UUID: ca552df1-bab1-45fa-9b9f-a7d23b4e5359
ORCID for Yi Huang: ORCID iD orcid.org/0000-0001-9259-8123
ORCID for Terence G. Langdon: ORCID iD orcid.org/0000-0003-3541-9250

Catalogue record

Date deposited: 27 Jan 2025 18:02
Last modified: 04 Jul 2025 04:01

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Contributors

Author: Abdelkader Khalfallah
Author: Sid Ahmed Amzert
Author: Fahd Arbaoui
Author: Nacereddine Titouche
Author: Noureddine Selmi
Author: Piotr Bazarnik
Author: Hiba Azzeddine
Author: Thierry Baudin
Author: François Brisset
Author: Yi Huang ORCID iD

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