The University of Southampton
University of Southampton Institutional Repository

Surface-enhanced Raman spectroscopy: a half-century historical perspective

Surface-enhanced Raman spectroscopy: a half-century historical perspective
Surface-enhanced Raman spectroscopy: a half-century historical perspective

Surface-enhanced Raman spectroscopy (SERS) has evolved significantly over fifty years into a powerful analytical technique. This review aims to achieve five main goals. (1) Providing a comprehensive history of SERS's discovery, its experimental and theoretical foundations, its connections to advances in nanoscience and plasmonics, and highlighting collective contributions of key pioneers. (2) Classifying four pivotal phases from the view of innovative methodologies in the fifty-year progression: initial development (mid-1970s to mid-1980s), downturn (mid-1980s to mid-1990s), nano-driven transformation (mid-1990s to mid-2010s), and recent boom (mid-2010s onwards). (3) Illuminating the entire journey and framework of SERS and its family members such as tip-enhanced Raman spectroscopy (TERS) and shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) and highlighting the trajectory. (4) Emphasizing the importance of innovative methods to overcome developmental bottlenecks, thereby expanding the material, morphology, and molecule generalities to leverage SERS as a versatile technique for broad applications. (5) Extracting the invaluable spirit of groundbreaking discovery and perseverant innovations from the pioneers and trailblazers. These key inspirations include proactively embracing and leveraging emerging scientific technologies, fostering interdisciplinary cooperation to transform the impossible into reality, and persistently searching to break bottlenecks even during low-tide periods, as luck is what happens when preparation meets opportunity.

0306-0012
Yi, Jun
e0535697-7a64-4661-8140-98f8a3bd6171
You, En Ming
34d7cf28-8265-47ac-bec6-ea14b7413d37
Hu, Ren
3738f18f-e942-4e45-adaf-6bb12a3085d8
Wu, De Yin
16fdcf8b-8f9f-4d5b-8044-af9545edbce3
Liu, Guo Kun
ba86667d-96a4-4546-8e0d-e3f5abda58e5
Yang, Zhi Lin
1d5ca622-425b-4c37-9025-4625a2602e35
Zhang, Hua
4e6d5ab0-0195-4d7b-bc48-a22562babb33
Gu, Yu
79c038ed-7a65-4c55-b2b5-e8ef1109aa60
Wang, Yao Hui
767f56f4-99c1-4a4d-aa1f-6c480a4a973e
Wang, Xiang
bb899a8b-ba6a-47f9-b48d-60746903da57
Ma, Hao
563110ca-679a-4a8b-a8e6-0e833680af27
Yang, Yang
0485bfa9-5186-45e8-92b7-37dfe00fbcf2
Liu, Jun Yang
44263121-e0fa-426a-85f4-926716437305
Fan, Feng Ru
d57370d2-26de-45f0-81fb-69784d1c6794
Zhan, Chao
7a3eb0e2-6ed7-4513-9efe-9e56db009798
Tian, Jing Hua
79081ed9-6484-46ab-848c-cbf13031522a
Qiao, Yu
e33cb63d-9f4d-4c3f-8412-aeb0405cb504
Wang, Hailong
09d63278-a65e-4895-ad62-8210419090ab
Luo, Si Heng
784ffbef-6dc3-47bd-ab62-73b069a078db
Meng, Zhao Dong
61595c70-6658-4d2e-92bc-e6fa20ee8879
Mao, Bing Wei
fe1dd32d-ff67-4111-bef7-33077e8b1185
Li, Jian Feng
5d25708f-1ef6-44ce-bc28-d9ea6dae7c14
Ren, Bin
9d4ce34c-3911-406c-a037-90b371c41937
Aizpurua, Javier
17705349-38e3-4089-adba-547d02449095
Apkarian, Vartkess Ara
04977c8d-3d60-41b4-8841-05107a538217
Bartlett, Philip N.
d99446db-a59d-4f89-96eb-f64b5d8bb075
Baumberg, Jeremy
68ab24f2-639e-43e2-b362-2a81deed5050
Bell, Steven E.J.
79a3f70f-108f-4c65-8f89-b1c47c7c66b4
Brolo, Alexandre G.
02a7412f-bf8a-455d-a5b4-a80629fa7ef8
Brus, Louis E.
2593a4f7-e6a7-48d5-831c-a6385255a641
Choo, Jaebum
e167a4f1-f59c-4fe7-b5c0-9a885efd3474
Cui, Li
79e3a336-beec-48a7-b020-f8cb0b3138b5
Deckert, Volker
1a005a8c-0610-4077-bdb8-b92de50702ab
Domke, Katrin F.
9b7c4599-b978-4083-a6c5-2b300aaee03e
Dong, Zhen Chao
f8e7df61-d221-4c76-ac9f-3f16b3ca1f64
Duan, Sai
cf96f328-f3ac-4115-bd87-32d970e7fc49
Faulds, Karen
4843572a-749c-4a7d-b7db-06553b9ef451
Frontiera, Renee
1bbdaa81-ad3f-4b27-aaaf-15dbdb34071d
Halas, Naomi
355fe8da-e2dd-43f9-a0c6-1aa106cff330
Haynes, Christy
bc5523b6-31f3-443d-abe0-183e28b2078e
Itoh, Tamitake
e14ac148-094f-4b18-a86d-7c9768711cfd
Kneipp, Janina
d29aa087-286e-4b1e-8f3f-a03fba66647e
Kneipp, Katrin
44d399bd-0f1a-47c7-b9b5-b48275d623d0
Le Ru, Eric C.
2b656b38-120e-46ae-9eb5-4ffc126b2938
Li, Zhi Peng
05f399b8-35ca-4ff1-8db3-a7b33105692d
Ling, Xing Yi
77ff84c2-97be-4ef7-9d6b-ff6fa7cfb2a1
Russell, Andrea E.
b6b7c748-efc1-4d5d-8a7a-8e4b69396169
Zhang, Jin
38372371-bf51-43f4-9f5e-7947b9f0b17a
Zhang, Yang
5d6180ab-5ea5-4aa7-b8b3-d8b4da85531c
Zhang, Yao
1b512f22-e660-481d-ae60-31d87344625f
et al.
Yi, Jun
e0535697-7a64-4661-8140-98f8a3bd6171
You, En Ming
34d7cf28-8265-47ac-bec6-ea14b7413d37
Hu, Ren
3738f18f-e942-4e45-adaf-6bb12a3085d8
Wu, De Yin
16fdcf8b-8f9f-4d5b-8044-af9545edbce3
Liu, Guo Kun
ba86667d-96a4-4546-8e0d-e3f5abda58e5
Yang, Zhi Lin
1d5ca622-425b-4c37-9025-4625a2602e35
Zhang, Hua
4e6d5ab0-0195-4d7b-bc48-a22562babb33
Gu, Yu
79c038ed-7a65-4c55-b2b5-e8ef1109aa60
Wang, Yao Hui
767f56f4-99c1-4a4d-aa1f-6c480a4a973e
Wang, Xiang
bb899a8b-ba6a-47f9-b48d-60746903da57
Ma, Hao
563110ca-679a-4a8b-a8e6-0e833680af27
Yang, Yang
0485bfa9-5186-45e8-92b7-37dfe00fbcf2
Liu, Jun Yang
44263121-e0fa-426a-85f4-926716437305
Fan, Feng Ru
d57370d2-26de-45f0-81fb-69784d1c6794
Zhan, Chao
7a3eb0e2-6ed7-4513-9efe-9e56db009798
Tian, Jing Hua
79081ed9-6484-46ab-848c-cbf13031522a
Qiao, Yu
e33cb63d-9f4d-4c3f-8412-aeb0405cb504
Wang, Hailong
09d63278-a65e-4895-ad62-8210419090ab
Luo, Si Heng
784ffbef-6dc3-47bd-ab62-73b069a078db
Meng, Zhao Dong
61595c70-6658-4d2e-92bc-e6fa20ee8879
Mao, Bing Wei
fe1dd32d-ff67-4111-bef7-33077e8b1185
Li, Jian Feng
5d25708f-1ef6-44ce-bc28-d9ea6dae7c14
Ren, Bin
9d4ce34c-3911-406c-a037-90b371c41937
Aizpurua, Javier
17705349-38e3-4089-adba-547d02449095
Apkarian, Vartkess Ara
04977c8d-3d60-41b4-8841-05107a538217
Bartlett, Philip N.
d99446db-a59d-4f89-96eb-f64b5d8bb075
Baumberg, Jeremy
68ab24f2-639e-43e2-b362-2a81deed5050
Bell, Steven E.J.
79a3f70f-108f-4c65-8f89-b1c47c7c66b4
Brolo, Alexandre G.
02a7412f-bf8a-455d-a5b4-a80629fa7ef8
Brus, Louis E.
2593a4f7-e6a7-48d5-831c-a6385255a641
Choo, Jaebum
e167a4f1-f59c-4fe7-b5c0-9a885efd3474
Cui, Li
79e3a336-beec-48a7-b020-f8cb0b3138b5
Deckert, Volker
1a005a8c-0610-4077-bdb8-b92de50702ab
Domke, Katrin F.
9b7c4599-b978-4083-a6c5-2b300aaee03e
Dong, Zhen Chao
f8e7df61-d221-4c76-ac9f-3f16b3ca1f64
Duan, Sai
cf96f328-f3ac-4115-bd87-32d970e7fc49
Faulds, Karen
4843572a-749c-4a7d-b7db-06553b9ef451
Frontiera, Renee
1bbdaa81-ad3f-4b27-aaaf-15dbdb34071d
Halas, Naomi
355fe8da-e2dd-43f9-a0c6-1aa106cff330
Haynes, Christy
bc5523b6-31f3-443d-abe0-183e28b2078e
Itoh, Tamitake
e14ac148-094f-4b18-a86d-7c9768711cfd
Kneipp, Janina
d29aa087-286e-4b1e-8f3f-a03fba66647e
Kneipp, Katrin
44d399bd-0f1a-47c7-b9b5-b48275d623d0
Le Ru, Eric C.
2b656b38-120e-46ae-9eb5-4ffc126b2938
Li, Zhi Peng
05f399b8-35ca-4ff1-8db3-a7b33105692d
Ling, Xing Yi
77ff84c2-97be-4ef7-9d6b-ff6fa7cfb2a1
Russell, Andrea E.
b6b7c748-efc1-4d5d-8a7a-8e4b69396169
Zhang, Jin
38372371-bf51-43f4-9f5e-7947b9f0b17a
Zhang, Yang
5d6180ab-5ea5-4aa7-b8b3-d8b4da85531c
Zhang, Yao
1b512f22-e660-481d-ae60-31d87344625f

Yi, Jun, You, En Ming and Hu, Ren , et al. (2024) Surface-enhanced Raman spectroscopy: a half-century historical perspective. Chemical Society Reviews. (doi:10.1039/d4cs00883a).

Record type: Review

Abstract

Surface-enhanced Raman spectroscopy (SERS) has evolved significantly over fifty years into a powerful analytical technique. This review aims to achieve five main goals. (1) Providing a comprehensive history of SERS's discovery, its experimental and theoretical foundations, its connections to advances in nanoscience and plasmonics, and highlighting collective contributions of key pioneers. (2) Classifying four pivotal phases from the view of innovative methodologies in the fifty-year progression: initial development (mid-1970s to mid-1980s), downturn (mid-1980s to mid-1990s), nano-driven transformation (mid-1990s to mid-2010s), and recent boom (mid-2010s onwards). (3) Illuminating the entire journey and framework of SERS and its family members such as tip-enhanced Raman spectroscopy (TERS) and shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) and highlighting the trajectory. (4) Emphasizing the importance of innovative methods to overcome developmental bottlenecks, thereby expanding the material, morphology, and molecule generalities to leverage SERS as a versatile technique for broad applications. (5) Extracting the invaluable spirit of groundbreaking discovery and perseverant innovations from the pioneers and trailblazers. These key inspirations include proactively embracing and leveraging emerging scientific technologies, fostering interdisciplinary cooperation to transform the impossible into reality, and persistently searching to break bottlenecks even during low-tide periods, as luck is what happens when preparation meets opportunity.

This record has no associated files available for download.

More information

Accepted/In Press date: 23 December 2024
e-pub ahead of print date: 23 December 2024

Identifiers

Local EPrints ID: 497833
URI: http://eprints.soton.ac.uk/id/eprint/497833
ISSN: 0306-0012
PURE UUID: 879fbb56-cf4c-414f-9e57-c94d61c50a2b
ORCID for Philip N. Bartlett: ORCID iD orcid.org/0000-0002-7300-6900
ORCID for Andrea E. Russell: ORCID iD orcid.org/0000-0002-8382-6443

Catalogue record

Date deposited: 03 Feb 2025 17:34
Last modified: 04 Feb 2025 02:36

Export record

Altmetrics

Contributors

Author: Jun Yi
Author: En Ming You
Author: Ren Hu
Author: De Yin Wu
Author: Guo Kun Liu
Author: Zhi Lin Yang
Author: Hua Zhang
Author: Yu Gu
Author: Yao Hui Wang
Author: Xiang Wang
Author: Hao Ma
Author: Yang Yang
Author: Jun Yang Liu
Author: Feng Ru Fan
Author: Chao Zhan
Author: Jing Hua Tian
Author: Yu Qiao
Author: Hailong Wang
Author: Si Heng Luo
Author: Zhao Dong Meng
Author: Bing Wei Mao
Author: Jian Feng Li
Author: Bin Ren
Author: Javier Aizpurua
Author: Vartkess Ara Apkarian
Author: Jeremy Baumberg
Author: Steven E.J. Bell
Author: Alexandre G. Brolo
Author: Louis E. Brus
Author: Jaebum Choo
Author: Li Cui
Author: Volker Deckert
Author: Katrin F. Domke
Author: Zhen Chao Dong
Author: Sai Duan
Author: Karen Faulds
Author: Renee Frontiera
Author: Naomi Halas
Author: Christy Haynes
Author: Tamitake Itoh
Author: Janina Kneipp
Author: Katrin Kneipp
Author: Eric C. Le Ru
Author: Zhi Peng Li
Author: Xing Yi Ling
Author: Jin Zhang
Author: Yang Zhang
Author: Yao Zhang
Corporate Author: et al.

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×