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The structure of C60Ph5Cl and C60Ph 5H, formed via electrophilic aromatic substitution

The structure of C60Ph5Cl and C60Ph 5H, formed via electrophilic aromatic substitution
The structure of C60Ph5Cl and C60Ph 5H, formed via electrophilic aromatic substitution

Reaction of C60Cl6 with benzene/FeCl 3yields C60Ph5Cl which is readily reduced to C60Ph5H, the main product of reacting C60 with Br2/FeCl3/benzene; both compounds have been characterised by NMR spectroscopy.

0022-4936
1463-1464
Avent, Anthony G.
6fe5d51d-5f31-454f-938a-ec91c840f2ce
Birkett, Paul R.
b8ed01c4-8787-472f-8353-683d3d006147
Crane, Jonathan D.
54fd5ae4-116f-4386-81c5-159bd5f4281b
Darwish, Adam D.
25f723f4-6a72-4e21-a361-76b275b617ef
Langley, G. John
7ac80d61-b91d-4261-ad17-255f94ea21ea
Kroto, Harold W.
fae3c2d3-3911-4c24-85d3-d61c8efe8e3e
Taylor, Roger
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Walton, David R.M.
b36cbf4c-6b27-4565-bc65-881153494026
Avent, Anthony G.
6fe5d51d-5f31-454f-938a-ec91c840f2ce
Birkett, Paul R.
b8ed01c4-8787-472f-8353-683d3d006147
Crane, Jonathan D.
54fd5ae4-116f-4386-81c5-159bd5f4281b
Darwish, Adam D.
25f723f4-6a72-4e21-a361-76b275b617ef
Langley, G. John
7ac80d61-b91d-4261-ad17-255f94ea21ea
Kroto, Harold W.
fae3c2d3-3911-4c24-85d3-d61c8efe8e3e
Taylor, Roger
16cca243-6646-4c6f-a563-321c2b1bb0f6
Walton, David R.M.
b36cbf4c-6b27-4565-bc65-881153494026

Avent, Anthony G., Birkett, Paul R., Crane, Jonathan D., Darwish, Adam D., Langley, G. John, Kroto, Harold W., Taylor, Roger and Walton, David R.M. (1994) The structure of C60Ph5Cl and C60Ph 5H, formed via electrophilic aromatic substitution. Journal of the Chemical Society, Chemical Communications, 1994 (12), 1463-1464. (doi:10.1039/C39940001463).

Record type: Article

Abstract

Reaction of C60Cl6 with benzene/FeCl 3yields C60Ph5Cl which is readily reduced to C60Ph5H, the main product of reacting C60 with Br2/FeCl3/benzene; both compounds have been characterised by NMR spectroscopy.

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Published date: 1994

Identifiers

Local EPrints ID: 498581
URI: http://eprints.soton.ac.uk/id/eprint/498581
ISSN: 0022-4936
PURE UUID: c7ce000d-1417-4b56-8a46-4a45d32fa485
ORCID for G. John Langley: ORCID iD orcid.org/0000-0002-8323-7235

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Date deposited: 21 Feb 2025 17:35
Last modified: 22 Feb 2025 02:34

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Contributors

Author: Anthony G. Avent
Author: Paul R. Birkett
Author: Jonathan D. Crane
Author: Adam D. Darwish
Author: G. John Langley ORCID iD
Author: Harold W. Kroto
Author: Roger Taylor
Author: David R.M. Walton

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