Modeling in restricted mixture experiment spaces for three mixture components
Modeling in restricted mixture experiment spaces for three mixture components
Quadratic models, fitted to data arising from mixture experiments with highly constrained ingredients proportions, often have large estimated coefficients that bear little resemblance to the size of the observations. Many practitioners find this disconcerting. Various transformations have been suggested to overcome this problem, although the predictions are unaffected by re-parameterizing the original terms in the model. We propose a new transformation of the coordinate system to the largest simplex that can be fitted inside the restricted region defined by the mixture constraints. In some cases the largest simplex will not be unique, in which case the one containing as many design points as possible is recommended. Then, the estimated coefficients will be much closer to the observations and thus more acceptable to the experimenter.
kronecker models, mixture constraints, mixture simplex, pseudo-components, quadratic response models, scheffé models, transformations, upper and lower bounds
207-217
Prescott, Philip
cf0adfdd-989b-4f15-9e60-ef85eed817b2
Draper, Norman R.
49cd917e-5e95-4c51-bc04-667cc2c46ec2
2009
Prescott, Philip
cf0adfdd-989b-4f15-9e60-ef85eed817b2
Draper, Norman R.
49cd917e-5e95-4c51-bc04-667cc2c46ec2
Prescott, Philip and Draper, Norman R.
(2009)
Modeling in restricted mixture experiment spaces for three mixture components.
Quality Technology and Quantitative Management, 6 (3), .
Abstract
Quadratic models, fitted to data arising from mixture experiments with highly constrained ingredients proportions, often have large estimated coefficients that bear little resemblance to the size of the observations. Many practitioners find this disconcerting. Various transformations have been suggested to overcome this problem, although the predictions are unaffected by re-parameterizing the original terms in the model. We propose a new transformation of the coordinate system to the largest simplex that can be fitted inside the restricted region defined by the mixture constraints. In some cases the largest simplex will not be unique, in which case the one containing as many design points as possible is recommended. Then, the estimated coefficients will be much closer to the observations and thus more acceptable to the experimenter.
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Submitted date: December 2007
Published date: 2009
Keywords:
kronecker models, mixture constraints, mixture simplex, pseudo-components, quadratic response models, scheffé models, transformations, upper and lower bounds
Organisations:
Statistics
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Local EPrints ID: 49870
URI: http://eprints.soton.ac.uk/id/eprint/49870
PURE UUID: fd4501f8-e135-41dd-9381-b242c6159a2a
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Date deposited: 07 Dec 2007
Last modified: 11 Dec 2021 16:56
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Author:
Norman R. Draper
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