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Propagation of chemical waves across inexcitable gaps

Propagation of chemical waves across inexcitable gaps
Propagation of chemical waves across inexcitable gaps
The propagation of chemical reaction–diffusion waves across a sequence of gaps is studied experimentally using catalyst-printed membranes. We find that a wave fails to propagate across the entire reaction domain if the width W of a gap is greater than a critical value Wcr or if the spacing S between two successive gaps is less than a critical value Scr. For values of W ≪ Wcr and S ≫ Scr then successful propagation across the entire domain is highly probable, irrespective of the number of gaps. For values of W and S close to the critical values, the probability of failure increases with increasing number of gaps.
1463-9076
Taylor, A.F.
08028a29-428d-4732-b6b1-f7a93389b386
Armstrong, G.R.
b8298644-6231-45f5-9de3-de4d0e6400cc
Goodchild, N.
ba45472e-ff8b-4034-a169-f18533579564
Scott, S.K.
cda3e63c-2ebc-41c3-8453-de40b89483a3
Taylor, A.F.
08028a29-428d-4732-b6b1-f7a93389b386
Armstrong, G.R.
b8298644-6231-45f5-9de3-de4d0e6400cc
Goodchild, N.
ba45472e-ff8b-4034-a169-f18533579564
Scott, S.K.
cda3e63c-2ebc-41c3-8453-de40b89483a3

Taylor, A.F., Armstrong, G.R., Goodchild, N. and Scott, S.K. (2003) Propagation of chemical waves across inexcitable gaps. Physical Chemistry Chemical Physics. (doi:10.1039/b305863h).

Record type: Article

Abstract

The propagation of chemical reaction–diffusion waves across a sequence of gaps is studied experimentally using catalyst-printed membranes. We find that a wave fails to propagate across the entire reaction domain if the width W of a gap is greater than a critical value Wcr or if the spacing S between two successive gaps is less than a critical value Scr. For values of W ≪ Wcr and S ≫ Scr then successful propagation across the entire domain is highly probable, irrespective of the number of gaps. For values of W and S close to the critical values, the probability of failure increases with increasing number of gaps.

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Published date: 27 May 2003

Identifiers

Local EPrints ID: 499477
URI: http://eprints.soton.ac.uk/id/eprint/499477
ISSN: 1463-9076
PURE UUID: 081d55d8-f107-4870-9e3e-d9476f300880
ORCID for A.F. Taylor: ORCID iD orcid.org/0000-0003-0071-8306

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Date deposited: 20 Mar 2025 18:23
Last modified: 21 Mar 2025 03:14

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Contributors

Author: A.F. Taylor ORCID iD
Author: G.R. Armstrong
Author: N. Goodchild
Author: S.K. Scott

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