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Interfacial liquid control to realize superior comprehensive properties of microwelded NiTi-stainless steel joints for multifunctional biomedical device fabrication

Interfacial liquid control to realize superior comprehensive properties of microwelded NiTi-stainless steel joints for multifunctional biomedical device fabrication
Interfacial liquid control to realize superior comprehensive properties of microwelded NiTi-stainless steel joints for multifunctional biomedical device fabrication
Dissimilar joining of NiTi and stainless steel (SS) is important in biomedical applications but poses significant challenges due to brittle intermetallic compounds (IMCs) formation in the welds. Replacing harmful phases in fusion welding cannot fully eliminate brittle IMCs and may introduce toxic elements, while the mixing restriction in solid-state welding increases the process complexity and results in large plastic deformation that degrades NiTi functional properties. In this work, we present a novel methodology that achieves a solid-state joined interface in NiTi-SS fusion welding (i.e., resistance microwelding) through in-situ interfacial liquid control. By combining the advantages of both welding techniques, the current method produced NiTi-SS joints with superior strength, superelasticity and biocompatibility compared to NiTi joints or base metal. The ultrathin reaction layer at the solid-state joined interface contributed
to a strong metallurgical bonding, while Joule heating effects and interfacial reactions enhanced superelasticity and biocompatibility of the joint. By demonstrating complete superelasticity on NiTi side, flexible deformation capacity on SS side, superior resistance to hydrogen embrittlement and electrochemical corrosion, and reduced Ni ion release and cytotoxicity, the welded joint shows great potential for the fabrication of multifunctional biomedical devices. Our work not only provides a comprehensive study of
NiTi-SS joining under the biomedical background, but also introduces a new strategy for controlling material interface and dissimilar-metal welding process.
NiTi, biocompatibility, intermetallic compounds, resistance welding, stainless steel, superelasticity, Resistance welding, Intermetallic compounds, Superelasticity, Stainless steel, Biocompatibility
1005-0302
304-318
Zhang, Kaiping
241f50e2-3411-440d-9810-b47a006e8ae6
Li, Jun
fdeeee61-081b-4207-aece-0289a04cf154
Anousheh, Amirsalar
6955504b-430d-481d-b5e4-2af716a810a5
Li, Jianxiong
40a1a8db-7f42-4b0f-b976-cf60672b9ccf
Parniani, Fatemeh
eff4db49-81f1-4b3f-84c5-f15221c91375
Zang, Chengwei
ca3808fd-eeed-42f3-8b0b-52b58e3e3365
Shirley Tang, Xiaowu
24e7ab24-f95c-4bcb-a1b5-159028a64fe5
Zhou, Y.Norman
1b472bde-2132-4c61-8c4a-0d752565188f
Peng, Peng
261b5236-517d-4b39-94a2-0ea2df3bffdc
Zhang, Kaiping
241f50e2-3411-440d-9810-b47a006e8ae6
Li, Jun
fdeeee61-081b-4207-aece-0289a04cf154
Anousheh, Amirsalar
6955504b-430d-481d-b5e4-2af716a810a5
Li, Jianxiong
40a1a8db-7f42-4b0f-b976-cf60672b9ccf
Parniani, Fatemeh
eff4db49-81f1-4b3f-84c5-f15221c91375
Zang, Chengwei
ca3808fd-eeed-42f3-8b0b-52b58e3e3365
Shirley Tang, Xiaowu
24e7ab24-f95c-4bcb-a1b5-159028a64fe5
Zhou, Y.Norman
1b472bde-2132-4c61-8c4a-0d752565188f
Peng, Peng
261b5236-517d-4b39-94a2-0ea2df3bffdc

Zhang, Kaiping, Li, Jun, Anousheh, Amirsalar, Li, Jianxiong, Parniani, Fatemeh, Zang, Chengwei, Shirley Tang, Xiaowu, Zhou, Y.Norman and Peng, Peng (2025) Interfacial liquid control to realize superior comprehensive properties of microwelded NiTi-stainless steel joints for multifunctional biomedical device fabrication. Journal of Materials Science and Technology, 233, 304-318. (doi:10.1016/j.jmst.2025.02.021).

Record type: Article

Abstract

Dissimilar joining of NiTi and stainless steel (SS) is important in biomedical applications but poses significant challenges due to brittle intermetallic compounds (IMCs) formation in the welds. Replacing harmful phases in fusion welding cannot fully eliminate brittle IMCs and may introduce toxic elements, while the mixing restriction in solid-state welding increases the process complexity and results in large plastic deformation that degrades NiTi functional properties. In this work, we present a novel methodology that achieves a solid-state joined interface in NiTi-SS fusion welding (i.e., resistance microwelding) through in-situ interfacial liquid control. By combining the advantages of both welding techniques, the current method produced NiTi-SS joints with superior strength, superelasticity and biocompatibility compared to NiTi joints or base metal. The ultrathin reaction layer at the solid-state joined interface contributed
to a strong metallurgical bonding, while Joule heating effects and interfacial reactions enhanced superelasticity and biocompatibility of the joint. By demonstrating complete superelasticity on NiTi side, flexible deformation capacity on SS side, superior resistance to hydrogen embrittlement and electrochemical corrosion, and reduced Ni ion release and cytotoxicity, the welded joint shows great potential for the fabrication of multifunctional biomedical devices. Our work not only provides a comprehensive study of
NiTi-SS joining under the biomedical background, but also introduces a new strategy for controlling material interface and dissimilar-metal welding process.

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Accepted/In Press date: 8 February 2025
e-pub ahead of print date: 14 March 2025
Published date: 4 April 2025
Keywords: NiTi, biocompatibility, intermetallic compounds, resistance welding, stainless steel, superelasticity, Resistance welding, Intermetallic compounds, Superelasticity, Stainless steel, Biocompatibility

Identifiers

Local EPrints ID: 502083
URI: http://eprints.soton.ac.uk/id/eprint/502083
ISSN: 1005-0302
PURE UUID: c3a89b77-9c5b-4ddc-a9f7-3e12ea4432e5
ORCID for Chengwei Zang: ORCID iD orcid.org/0009-0004-6609-1598

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Date deposited: 16 Jun 2025 16:43
Last modified: 04 Sep 2025 02:37

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Contributors

Author: Kaiping Zhang
Author: Jun Li
Author: Amirsalar Anousheh
Author: Jianxiong Li
Author: Fatemeh Parniani
Author: Chengwei Zang ORCID iD
Author: Xiaowu Shirley Tang
Author: Y.Norman Zhou
Author: Peng Peng

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