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Analysis of plumes produced by novel ionic liquids in electrospray thrusters

Analysis of plumes produced by novel ionic liquids in electrospray thrusters
Analysis of plumes produced by novel ionic liquids in electrospray thrusters
A single emitter electrospray thruster was tested with four ionic liquids, which have not been tested before, in order to investigate the physics of ion emission. Two of these ionic liquids had metal/metalloid halides anions, similar to 1-ethyl-3-methylimidazolium tetrafluroborate, and were found to emit similar to greater currents than typically found with EMIBF4. 1-Ethyl-3-methylimidazolium tetrachloroferrate was found to emit up to +50.7/-33.6µA and 1-ethyl-3-methylimidazolium hexafluoroantimonate up to +12.6/-14.5 µA, compared to +18.3/-9.3 µA for 1-ethyl-3-methylimidazolium tetrafluoroborate. Two further propellants were investigated formed of very novel ionic liquids which have multiple charges on the ions within them, and hence termed multiply charged ionic liquids. These were found to emit reduced currents, with up to +11.4/-5.3 µA by bis(3-methylimidazolium) hexyltetrakis (hexathiocyanato) cobaltate and up to +2.1/-2.2 µA being emitted by tris(1-hexyl-3-methylimidazolium) dysprosium(III) hexathiocyanate. All four of these ionic liquids were shown to emit a purely ionic plume, despite having widely varying propellant properties.
Dworski, Szymon
433c1ca7-098e-4d48-89b2-0c46d18cc635
Ryan, Charlie N.
3627e47b-01b8-4ddb-b248-4243aad1f872
Dworski, Szymon
433c1ca7-098e-4d48-89b2-0c46d18cc635
Ryan, Charlie N.
3627e47b-01b8-4ddb-b248-4243aad1f872

Dworski, Szymon and Ryan, Charlie N. (2025) Analysis of plumes produced by novel ionic liquids in electrospray thrusters. 38th International Electric Propulsion Conference (IEPC 2024), , Toulouse, France. 23 - 28 Jun 2025. 19 pp .

Record type: Conference or Workshop Item (Paper)

Abstract

A single emitter electrospray thruster was tested with four ionic liquids, which have not been tested before, in order to investigate the physics of ion emission. Two of these ionic liquids had metal/metalloid halides anions, similar to 1-ethyl-3-methylimidazolium tetrafluroborate, and were found to emit similar to greater currents than typically found with EMIBF4. 1-Ethyl-3-methylimidazolium tetrachloroferrate was found to emit up to +50.7/-33.6µA and 1-ethyl-3-methylimidazolium hexafluoroantimonate up to +12.6/-14.5 µA, compared to +18.3/-9.3 µA for 1-ethyl-3-methylimidazolium tetrafluoroborate. Two further propellants were investigated formed of very novel ionic liquids which have multiple charges on the ions within them, and hence termed multiply charged ionic liquids. These were found to emit reduced currents, with up to +11.4/-5.3 µA by bis(3-methylimidazolium) hexyltetrakis (hexathiocyanato) cobaltate and up to +2.1/-2.2 µA being emitted by tris(1-hexyl-3-methylimidazolium) dysprosium(III) hexathiocyanate. All four of these ionic liquids were shown to emit a purely ionic plume, despite having widely varying propellant properties.

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Published date: 23 June 2025
Venue - Dates: 38th International Electric Propulsion Conference (IEPC 2024), , Toulouse, France, 2025-06-23 - 2025-06-28

Identifiers

Local EPrints ID: 503525
URI: http://eprints.soton.ac.uk/id/eprint/503525
PURE UUID: 2c69521e-4c77-4597-bc29-d1a124851184

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Date deposited: 04 Aug 2025 16:54
Last modified: 04 Aug 2025 16:54

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Contributors

Author: Szymon Dworski
Author: Charlie N. Ryan

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