Metathesis and the building block approach to novel layered copper oxyselenides – useful tool or synthetic dead-end?
Metathesis and the building block approach to novel layered copper oxyselenides – useful tool or synthetic dead-end?
The use of metathesis, or ionic double displacement reactions, for the synthesis of layered copper oxyselenides is explored, and compared to the conventional solid state reaction approach across a range of temperatures. We have determined that metathesis does offer some advantages in product selectivity at low temperature but due to more complex synthetic requirements does not warrant more widespread adoption.
Kemp, Liam
82904c87-e2d8-410b-b338-aa823636fa11
Hyett, Geoffrey
4f292fc9-2198-4b18-99b9-3c74e7dfed8d
Kemp, Liam
82904c87-e2d8-410b-b338-aa823636fa11
Hyett, Geoffrey
4f292fc9-2198-4b18-99b9-3c74e7dfed8d
Kemp, Liam and Hyett, Geoffrey
(2025)
Metathesis and the building block approach to novel layered copper oxyselenides – useful tool or synthetic dead-end?
Materials Horizons.
(doi:10.1039/D5MH01350J).
Abstract
The use of metathesis, or ionic double displacement reactions, for the synthesis of layered copper oxyselenides is explored, and compared to the conventional solid state reaction approach across a range of temperatures. We have determined that metathesis does offer some advantages in product selectivity at low temperature but due to more complex synthetic requirements does not warrant more widespread adoption.
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Accepted/In Press date: 27 August 2025
e-pub ahead of print date: 28 August 2025
Identifiers
Local EPrints ID: 505540
URI: http://eprints.soton.ac.uk/id/eprint/505540
ISSN: 2051-6355
PURE UUID: 3c3ca7d2-0653-43e4-929b-12665d59b7f7
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Date deposited: 13 Oct 2025 16:52
Last modified: 14 Oct 2025 01:47
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Author:
Liam Kemp
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