Uncertainty analysis for the design, operation, and management of proton exchange membrane fuel cells
Uncertainty analysis for the design, operation, and management of proton exchange membrane fuel cells
Proton exchange membrane fuel cell (PEMFC) holds great promise due to its zero carbon emission and high energy conversion efficiency. However, improper design and operation can cause performance failures and accelerated degradation. A key challenge in modeling-based optimization is accounting for inherent randomness and operating disturbances, which calls for predictive models that incorporate uncertainty. In recent years, uncertainty analysis using advanced statistical and machine learning techniques has attracted growing attention for guiding the development of energy systems. Despite this progress, comprehensive reviews that link uncertainty analysis to performance enhancement of PEMFCs and their integrated power systems remain limited; existing PEMFC reviews mainly emphasize mechanistic, data-driven, and control-oriented modeling, while the crucial role of uncertainty analysis in these frameworks is only briefly addressed. This review summarizes PEMFC modeling approaches and uncertainty analytical techniques and keeps the reader abreast of recent advances of uncertainty analysis in the designs and management of PEMFCs. Moreover, this review discusses limitations in reliability and interpretability on uncertainty analysis and proposes directions for future research to construct more robust and trustworthy optimization strategies. Ultimately, this review aims to provide a comprehensive guide for applying uncertainty analysis to improve the design, control, and long-term stability of PEMFC systems.
proton exchange membrane fuel cell, uncertainty analysis, modeling, Randomness, System disturbance, Machine learning
Li, Zhejun
ab84102c-2025-4d8b-9837-bbf52c20a9c3
Mao, Qing
00ff4c15-9686-4c3a-813f-7d81d939a978
Wu, Haixu
ab5d97e2-e340-4b61-be6f-685c34c60859
Chong, Jeng Yi
2f9ead94-86f2-4e20-9e67-75f10759555b
Zhang, Ping
0644a222-8d74-4a3d-a4e3-a8eb4b30a98f
24 December 2025
Li, Zhejun
ab84102c-2025-4d8b-9837-bbf52c20a9c3
Mao, Qing
00ff4c15-9686-4c3a-813f-7d81d939a978
Wu, Haixu
ab5d97e2-e340-4b61-be6f-685c34c60859
Chong, Jeng Yi
2f9ead94-86f2-4e20-9e67-75f10759555b
Zhang, Ping
0644a222-8d74-4a3d-a4e3-a8eb4b30a98f
Li, Zhejun, Mao, Qing, Wu, Haixu, Chong, Jeng Yi and Zhang, Ping
(2025)
Uncertainty analysis for the design, operation, and management of proton exchange membrane fuel cells.
Journal of Power Sources, 666, [239142].
(doi:10.1016/j.jpowsour.2025.239142).
Abstract
Proton exchange membrane fuel cell (PEMFC) holds great promise due to its zero carbon emission and high energy conversion efficiency. However, improper design and operation can cause performance failures and accelerated degradation. A key challenge in modeling-based optimization is accounting for inherent randomness and operating disturbances, which calls for predictive models that incorporate uncertainty. In recent years, uncertainty analysis using advanced statistical and machine learning techniques has attracted growing attention for guiding the development of energy systems. Despite this progress, comprehensive reviews that link uncertainty analysis to performance enhancement of PEMFCs and their integrated power systems remain limited; existing PEMFC reviews mainly emphasize mechanistic, data-driven, and control-oriented modeling, while the crucial role of uncertainty analysis in these frameworks is only briefly addressed. This review summarizes PEMFC modeling approaches and uncertainty analytical techniques and keeps the reader abreast of recent advances of uncertainty analysis in the designs and management of PEMFCs. Moreover, this review discusses limitations in reliability and interpretability on uncertainty analysis and proposes directions for future research to construct more robust and trustworthy optimization strategies. Ultimately, this review aims to provide a comprehensive guide for applying uncertainty analysis to improve the design, control, and long-term stability of PEMFC systems.
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PEMFC_Review_Revised_FINAL
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Accepted/In Press date: 17 December 2025
e-pub ahead of print date: 24 December 2025
Published date: 24 December 2025
Keywords:
proton exchange membrane fuel cell, uncertainty analysis, modeling, Randomness, System disturbance, Machine learning
Identifiers
Local EPrints ID: 509045
URI: http://eprints.soton.ac.uk/id/eprint/509045
ISSN: 0378-7753
PURE UUID: 9f9c683d-b882-45d2-bf19-c12e015d8d50
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Date deposited: 10 Feb 2026 17:49
Last modified: 11 Feb 2026 03:12
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Contributors
Author:
Zhejun Li
Author:
Qing Mao
Author:
Haixu Wu
Author:
Jeng Yi Chong
Author:
Ping Zhang
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