Carbon isotope exchange and transfer reactions involving CO2
Carbon isotope exchange and transfer reactions involving CO2
Carboxylation reactions are fundamental transformations in organic chemistry, enabling the synthesis of diverse and valuable compounds, including polymers, pharmaceuticals, and agrochemicals. In recent years, carboxylation processes proceeding via carbon isotope exchange or CO2 transfer have received significant interest. These processes offer intriguing decarboxylation/carboxylation reactivity and enhance existing carboxylation pathways, in particular by delivering efficient and sustainable solutions for carbon isotope labelling. This review compares and contrasts the related fields of carbon isotope exchange and transfer reactions involving CO2. We detail early developments to the most recent advancements and discuss the advantages and limitations of each approach, in particular with regard to the efficiency of each strategy.
Beaver, Grace E.
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Marris, Katherine E.
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Ryder-Mahoney, Daniel J.
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Tzaras, Dimitrios Ioannis
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Bragg, Ryan A.
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Elmore, Charles S.
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Perry, Gregory J.P.
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Beaver, Grace E.
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Marris, Katherine E.
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Ryder-Mahoney, Daniel J.
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Tzaras, Dimitrios Ioannis
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Bragg, Ryan A.
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Elmore, Charles S.
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Perry, Gregory J.P.
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Beaver, Grace E., Marris, Katherine E., Ryder-Mahoney, Daniel J., Tzaras, Dimitrios Ioannis, Bragg, Ryan A., Elmore, Charles S. and Perry, Gregory J.P.
(2026)
Carbon isotope exchange and transfer reactions involving CO2.
Organic Chemistry Frontiers.
(doi:10.1039/D6QO00133E.).
Abstract
Carboxylation reactions are fundamental transformations in organic chemistry, enabling the synthesis of diverse and valuable compounds, including polymers, pharmaceuticals, and agrochemicals. In recent years, carboxylation processes proceeding via carbon isotope exchange or CO2 transfer have received significant interest. These processes offer intriguing decarboxylation/carboxylation reactivity and enhance existing carboxylation pathways, in particular by delivering efficient and sustainable solutions for carbon isotope labelling. This review compares and contrasts the related fields of carbon isotope exchange and transfer reactions involving CO2. We detail early developments to the most recent advancements and discuss the advantages and limitations of each approach, in particular with regard to the efficiency of each strategy.
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d6qo00133e
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Accepted/In Press date: 27 March 2026
e-pub ahead of print date: 30 March 2026
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Local EPrints ID: 511498
URI: http://eprints.soton.ac.uk/id/eprint/511498
ISSN: 2052-4129
PURE UUID: 7c0117c9-cdf1-49cb-8b79-3a6359e4acf0
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Date deposited: 18 May 2026 16:38
Last modified: 19 May 2026 02:13
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Author:
Grace E. Beaver
Author:
Katherine E. Marris
Author:
Daniel J. Ryder-Mahoney
Author:
Dimitrios Ioannis Tzaras
Author:
Ryan A. Bragg
Author:
Charles S. Elmore
Author:
Gregory J.P. Perry
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