The University of Southampton
University of Southampton Institutional Repository

On the similarity in catalytic activity of homogeneous and heterogeneous Cr(VI) catalysts in the decomposition of cyclohexyl hydroperoxide

Buijs, W., Raja, R., Thomas, J. M. and Wolters, H. (2003) On the similarity in catalytic activity of homogeneous and heterogeneous Cr(VI) catalysts in the decomposition of cyclohexyl hydroperoxide Catalysis Letters, 91, (3-4), pp. 253-259. (doi:10.1023/B:CATL.0000007162.32473.85).

Record type: Article

Abstract

Pyridinium dichromate, chromium trioxide and CrAlPO-5 showed a very similar selectivity pattern in the decomposition of cyclohexyl hydroperoxide. CrAPO-5 turned out to be a real heterogeneous catalyst, most likely acting via a similar mechanism to the homogeneous catalysts. Molecular modeling indicates that heterolytic decomposition of the intermediate cyclohexyl peroxychromate ester yields cyclohexanone and H2CrO4 via a cyclic transition state.

Full text not available from this repository.

More information

Published date: 2003
Keywords: cyclohexane oxidation, chromium, cralpo-5, cyclohexyl hydroperoxide decomposition, molecular modeling, liquid-phase oxidations

Identifiers

Local EPrints ID: 54165
URI: http://eprints.soton.ac.uk/id/eprint/54165
ISSN: 1011-372X
PURE UUID: ef1c3ae8-9797-448f-aa31-e1f2db35c550
ORCID for R. Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 31 Jul 2008
Last modified: 17 Jul 2017 14:36

Export record

Altmetrics

Contributors

Author: W. Buijs
Author: R. Raja ORCID iD
Author: J. M. Thomas
Author: H. Wolters

University divisions

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×