Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl)
Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl)
The reactions of [MeAl(2-py)3Li·thf]( 1) with FeCl2 or Cp2Mn in toluene–thf give simple access to the Group 13–transition metal heterometallic complexes [{MeAl(2-py)3}2M][M = Fe ( 2), Mn ( 3)]; complex 2 has been shown to be a highly selective styrene epoxidation catalyst in air.
catalysts, cu, molecular-oxygen, h2o2, iron(ii), chemistry, spin, olefins, ligands, contact
198-200
Alvarez, C.S.
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Garcia, F.
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Humphrey, S.M.
de5b5540-3e2d-4228-9ce8-8e0fa3e6b25e
Hopkins, A.D.
2b616efe-01a8-4278-859b-425e07add42b
Kowenicki, R.A.
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McPartin, M.
e645677c-81cf-4beb-9d31-40a253d0b384
Layfield, R.A.
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Raja, R.
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Rogers, M.C.
c5c7bc65-fa1a-4ea2-8c77-d242d27bc21c
Woods, A.D.
19a309ae-8bb4-47f5-a590-26e7dec356bc
Wright, D.S.
0981c6a0-1639-43e5-9e85-8c856cbdda8e
2005
Alvarez, C.S.
23e9babd-d7c0-42e2-aec4-c9ecf5c1c7c2
Garcia, F.
22f7c9f7-815d-449e-ac82-f5fcb8c107c7
Humphrey, S.M.
de5b5540-3e2d-4228-9ce8-8e0fa3e6b25e
Hopkins, A.D.
2b616efe-01a8-4278-859b-425e07add42b
Kowenicki, R.A.
95656823-8e17-4a1c-b2c3-b0ed06c3be70
McPartin, M.
e645677c-81cf-4beb-9d31-40a253d0b384
Layfield, R.A.
b3dc2e10-5b66-4ff5-a472-b178a29a6ce6
Raja, R.
74faf442-38a6-4ac1-84f9-b3c039cb392b
Rogers, M.C.
c5c7bc65-fa1a-4ea2-8c77-d242d27bc21c
Woods, A.D.
19a309ae-8bb4-47f5-a590-26e7dec356bc
Wright, D.S.
0981c6a0-1639-43e5-9e85-8c856cbdda8e
Alvarez, C.S., Garcia, F., Humphrey, S.M., Hopkins, A.D., Kowenicki, R.A., McPartin, M., Layfield, R.A., Raja, R., Rogers, M.C., Woods, A.D. and Wright, D.S.
(2005)
Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl).
Chemical Communications, (2), .
(doi:10.1039/b413488e).
Abstract
The reactions of [MeAl(2-py)3Li·thf]( 1) with FeCl2 or Cp2Mn in toluene–thf give simple access to the Group 13–transition metal heterometallic complexes [{MeAl(2-py)3}2M][M = Fe ( 2), Mn ( 3)]; complex 2 has been shown to be a highly selective styrene epoxidation catalyst in air.
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Published date: 2005
Keywords:
catalysts, cu, molecular-oxygen, h2o2, iron(ii), chemistry, spin, olefins, ligands, contact
Identifiers
Local EPrints ID: 54190
URI: http://eprints.soton.ac.uk/id/eprint/54190
ISSN: 1359-7345
PURE UUID: a2555fd7-9025-460e-b23c-c16513b4351e
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Date deposited: 31 Jul 2008
Last modified: 16 Mar 2024 03:51
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Contributors
Author:
C.S. Alvarez
Author:
F. Garcia
Author:
S.M. Humphrey
Author:
A.D. Hopkins
Author:
R.A. Kowenicki
Author:
M. McPartin
Author:
R.A. Layfield
Author:
M.C. Rogers
Author:
A.D. Woods
Author:
D.S. Wright
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