Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl)


Alvarez, C.S., Garcia, F., Humphrey, S.M., Hopkins, A.D., Kowenicki, R.A., McPartin, M., Layfield, R.A., Raja, R., Rogers, M.C., Woods, A.D. and Wright, D.S. (2005) Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl) Chemical Communications, (2), pp. 198-200. (doi:10.1039/b413488e).

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Description/Abstract

The reactions of [MeAl(2-py)3Li·thf]( 1) with FeCl2 or Cp2Mn in toluene–thf give simple access to the Group 13–transition metal heterometallic complexes [{MeAl(2-py)3}2M][M = Fe ( 2), Mn ( 3)]; complex 2 has been shown to be a highly selective styrene epoxidation catalyst in air.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1039/b413488e
ISSNs: 1359-7345 (print)
Keywords: catalysts, cu, molecular-oxygen, h2o2, iron(ii), chemistry, spin, olefins, ligands, contact
Subjects:
ePrint ID: 54190
Date :
Date Event
2005Published
Date Deposited: 31 Jul 2008
Last Modified: 16 Apr 2017 17:47
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/54190

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