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Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl)

Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl)
Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl)
The reactions of [MeAl(2-py)3Li·thf]( 1) with FeCl2 or Cp2Mn in toluene–thf give simple access to the Group 13–transition metal heterometallic complexes [{MeAl(2-py)3}2M][M = Fe ( 2), Mn ( 3)]; complex 2 has been shown to be a highly selective styrene epoxidation catalyst in air.
catalysts, cu, molecular-oxygen, h2o2, iron(ii), chemistry, spin, olefins, ligands, contact
1359-7345
198-200
Alvarez, C.S.
23e9babd-d7c0-42e2-aec4-c9ecf5c1c7c2
Garcia, F.
22f7c9f7-815d-449e-ac82-f5fcb8c107c7
Humphrey, S.M.
de5b5540-3e2d-4228-9ce8-8e0fa3e6b25e
Hopkins, A.D.
2b616efe-01a8-4278-859b-425e07add42b
Kowenicki, R.A.
95656823-8e17-4a1c-b2c3-b0ed06c3be70
McPartin, M.
e645677c-81cf-4beb-9d31-40a253d0b384
Layfield, R.A.
b3dc2e10-5b66-4ff5-a472-b178a29a6ce6
Raja, R.
74faf442-38a6-4ac1-84f9-b3c039cb392b
Rogers, M.C.
c5c7bc65-fa1a-4ea2-8c77-d242d27bc21c
Woods, A.D.
19a309ae-8bb4-47f5-a590-26e7dec356bc
Wright, D.S.
0981c6a0-1639-43e5-9e85-8c856cbdda8e
Alvarez, C.S.
23e9babd-d7c0-42e2-aec4-c9ecf5c1c7c2
Garcia, F.
22f7c9f7-815d-449e-ac82-f5fcb8c107c7
Humphrey, S.M.
de5b5540-3e2d-4228-9ce8-8e0fa3e6b25e
Hopkins, A.D.
2b616efe-01a8-4278-859b-425e07add42b
Kowenicki, R.A.
95656823-8e17-4a1c-b2c3-b0ed06c3be70
McPartin, M.
e645677c-81cf-4beb-9d31-40a253d0b384
Layfield, R.A.
b3dc2e10-5b66-4ff5-a472-b178a29a6ce6
Raja, R.
74faf442-38a6-4ac1-84f9-b3c039cb392b
Rogers, M.C.
c5c7bc65-fa1a-4ea2-8c77-d242d27bc21c
Woods, A.D.
19a309ae-8bb4-47f5-a590-26e7dec356bc
Wright, D.S.
0981c6a0-1639-43e5-9e85-8c856cbdda8e

Alvarez, C.S., Garcia, F., Humphrey, S.M., Hopkins, A.D., Kowenicki, R.A., McPartin, M., Layfield, R.A., Raja, R., Rogers, M.C., Woods, A.D. and Wright, D.S. (2005) Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl). Chemical Communications, (2), 198-200. (doi:10.1039/b413488e).

Record type: Article

Abstract

The reactions of [MeAl(2-py)3Li·thf]( 1) with FeCl2 or Cp2Mn in toluene–thf give simple access to the Group 13–transition metal heterometallic complexes [{MeAl(2-py)3}2M][M = Fe ( 2), Mn ( 3)]; complex 2 has been shown to be a highly selective styrene epoxidation catalyst in air.

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More information

Published date: 2005
Keywords: catalysts, cu, molecular-oxygen, h2o2, iron(ii), chemistry, spin, olefins, ligands, contact

Identifiers

Local EPrints ID: 54190
URI: https://eprints.soton.ac.uk/id/eprint/54190
ISSN: 1359-7345
PURE UUID: a2555fd7-9025-460e-b23c-c16513b4351e
ORCID for R. Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 31 Jul 2008
Last modified: 14 Mar 2019 01:41

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Contributors

Author: C.S. Alvarez
Author: F. Garcia
Author: S.M. Humphrey
Author: A.D. Hopkins
Author: R.A. Kowenicki
Author: M. McPartin
Author: R.A. Layfield
Author: R. Raja ORCID iD
Author: M.C. Rogers
Author: A.D. Woods
Author: D.S. Wright

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