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Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl)

Alvarez, C.S., Garcia, F., Humphrey, S.M., Hopkins, A.D., Kowenicki, R.A., McPartin, M., Layfield, R.A., Raja, R., Rogers, M.C., Woods, A.D. and Wright, D.S. (2005) Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl) Chemical Communications, (2), pp. 198-200. (doi:10.1039/b413488e).

Record type: Article

Abstract

The reactions of [MeAl(2-py)3Li·thf]( 1) with FeCl2 or Cp2Mn in toluene–thf give simple access to the Group 13–transition metal heterometallic complexes [{MeAl(2-py)3}2M][M = Fe ( 2), Mn ( 3)]; complex 2 has been shown to be a highly selective styrene epoxidation catalyst in air.

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More information

Published date: 2005
Keywords: catalysts, cu, molecular-oxygen, h2o2, iron(ii), chemistry, spin, olefins, ligands, contact

Identifiers

Local EPrints ID: 54190
URI: http://eprints.soton.ac.uk/id/eprint/54190
ISSN: 1359-7345
PURE UUID: a2555fd7-9025-460e-b23c-c16513b4351e
ORCID for R. Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 31 Jul 2008
Last modified: 17 Jul 2017 14:36

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Contributors

Author: C.S. Alvarez
Author: F. Garcia
Author: S.M. Humphrey
Author: A.D. Hopkins
Author: R.A. Kowenicki
Author: M. McPartin
Author: R.A. Layfield
Author: R. Raja ORCID iD
Author: M.C. Rogers
Author: A.D. Woods
Author: D.S. Wright

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