Predictable and unpredictable reactions between 4,4 '-dipyridyldisulfide and phosphonodithioato/dithiophosphato Ni-II complexes: novel coordination polymers and the unique example of 4,4 '-dipyridyltrisulfide


Aragoni, M.C., Arca, M., Crespo, M., Devillanova, F.A., Hursthouse, M.B., Huth, S.L., Isaia, F., Lippolis, V. and Verani, G. (2007) Predictable and unpredictable reactions between 4,4 '-dipyridyldisulfide and phosphonodithioato/dithiophosphato Ni-II complexes: novel coordination polymers and the unique example of 4,4 '-dipyridyltrisulfide CrystEngComm, 9, (10), pp. 873-878. (doi:10.1039/b708972d).

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Description/Abstract

The reactions between dpds and the phosphonodithioato and dithiophosphato NiII complexes [Ni(MeOpdt)2] (1), [Ni(EtOpdt)2] (2), and [Ni((EtO)2PS2)2] (3) yielded the novel coordination polymers ( 1·dpds), ( 2·dpts), and ( 3·dps), featuring three different spacers ensuing from in situ chemical rearrangement of the starting dpds reagent (dpds, 4,4-dipyridyldisulfide; dps, 4,4-dipyridylmonosulfide; dpts, 4,4-dipyridyltrisulfide).

Item Type: Article
Digital Object Identifier (DOI): doi:10.1039/b708972d
ISSNs: 1466-8033 (print)
Keywords: bonds, chemistry, ligands, s-s, disulfide, cleavage, reactivity, solids, framework
Subjects:
ePrint ID: 54233
Date :
Date Event
2007Published
Date Deposited: 31 Jul 2008
Last Modified: 16 Apr 2017 17:47
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/54233

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