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Predictable and unpredictable reactions between 4,4 '-dipyridyldisulfide and phosphonodithioato/dithiophosphato Ni-II complexes: novel coordination polymers and the unique example of 4,4 '-dipyridyltrisulfide

Aragoni, M.C., Arca, M., Crespo, M., Devillanova, F.A., Hursthouse, M.B., Huth, S.L., Isaia, F., Lippolis, V. and Verani, G. (2007) Predictable and unpredictable reactions between 4,4 '-dipyridyldisulfide and phosphonodithioato/dithiophosphato Ni-II complexes: novel coordination polymers and the unique example of 4,4 '-dipyridyltrisulfide CrystEngComm, 9, (10), pp. 873-878. (doi:10.1039/b708972d).

Record type: Article

Abstract

The reactions between dpds and the phosphonodithioato and dithiophosphato NiII complexes [Ni(MeOpdt)2] (1), [Ni(EtOpdt)2] (2), and [Ni((EtO)2PS2)2] (3) yielded the novel coordination polymers ( 1·dpds), ( 2·dpts), and ( 3·dps), featuring three different spacers ensuing from in situ chemical rearrangement of the starting dpds reagent (dpds, 4,4-dipyridyldisulfide; dps, 4,4-dipyridylmonosulfide; dpts, 4,4-dipyridyltrisulfide).

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Published date: 2007
Keywords: bonds, chemistry, ligands, s-s, disulfide, cleavage, reactivity, solids, framework

Identifiers

Local EPrints ID: 54233
URI: http://eprints.soton.ac.uk/id/eprint/54233
ISSN: 1466-8033
PURE UUID: 67fc2e0f-6905-4d42-9784-953e6ca8b48b

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Date deposited: 31 Jul 2008
Last modified: 17 Jul 2017 14:36

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Contributors

Author: M.C. Aragoni
Author: M. Arca
Author: M. Crespo
Author: F.A. Devillanova
Author: M.B. Hursthouse
Author: S.L. Huth
Author: F. Isaia
Author: V. Lippolis
Author: G. Verani

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