The University of Southampton
University of Southampton Institutional Repository

Charge-transfer adducts of N-methylthiazolidine-2-thione with IBr and I-2: An example of polymorphism featuring interpenetrating three-dimensional subcomponent assemblies and halogen center dot center dot center dot pi center dot center dot center dot halogen weak interactions

Record type: Article

Two polymorphic forms of the 1:1 charge-transfer adduct between N-methylthiazolidine-2-thione and IBr have been isolated: their structural analyses by a recently reported procedure for comparison of multiple crystal forms of the same molecular structure reveal some interesting geometrical 3D similarity relationships that can be interpreted in terms of different sets of halogen ······halogen weak interactions. The 1:1 charge-transfer adduct with I2 has also been isolated and structurally characterized and proven to be isostructural with one of the two polymorphic forms of the IBr adduct.

Full text not available from this repository.

Citation

Aragoni, M.C., Arca, M., Demartin, F., Devillanova, F.A., Gelbrich, T., Garau, A., Hursthouse, M.B., Isaia, F. and Lippolis, V. (2007) Charge-transfer adducts of N-methylthiazolidine-2-thione with IBr and I-2: An example of polymorphism featuring interpenetrating three-dimensional subcomponent assemblies and halogen center dot center dot center dot pi center dot center dot center dot halogen weak interactions Crystal Growth & Design, 7, (7), pp. 1284-1290. (doi:10.1021/cg0606545).

More information

Published date: 2007
Keywords: spectroscopy, differential scanning calorimetry, polymorphism, parameters, crystallization, hydrochloride, powder diffraction, forms, crystal, phase, local-anesthetic drugs

Identifiers

Local EPrints ID: 54234
URI: http://eprints.soton.ac.uk/id/eprint/54234
ISSN: 1528-7483
PURE UUID: dadf7650-f2e9-40c5-9a1e-899d27bbf53a

Catalogue record

Date deposited: 31 Jul 2008
Last modified: 17 Jul 2017 14:36

Export record

Altmetrics

Contributors

Author: M.C. Aragoni
Author: M. Arca
Author: F. Demartin
Author: F.A. Devillanova
Author: T. Gelbrich
Author: A. Garau
Author: M.B. Hursthouse
Author: F. Isaia
Author: V. Lippolis

University divisions


Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×