An unprecedented polyborate ester anion: X-ray diffraction studies on [1,8-C10H6(NMe2)(2)H][B5O6(OMe)(4)]
An unprecedented polyborate ester anion: X-ray diffraction studies on [1,8-C10H6(NMe2)(2)H][B5O6(OMe)(4)]
The slow hydrolysis of B(OMe)3 in a CH2Cl2 solution in the presence of 1,8-C10H6(NMe2)2 (5:1 ratio) led to the formation of the novel isolated pentaborate ester anion [B5O6(OMe)4]-, which was characterized by a single-crystal X-ray diffraction study as the salt [1,8-C10H6(NMe2)2H][B5O6(OMe)4].
boric-acid, pentaborate, 1st examples, arylboronic acids
3801-3803
Beckett, M.A.C.C.
32ebf914-453e-4fe8-9e30-366d6cd25711
Horton, P.N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Varma, K.S.
4ee3651b-b672-4641-8f18-0b838e387620
2007
Beckett, M.A.C.C.
32ebf914-453e-4fe8-9e30-366d6cd25711
Horton, P.N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Varma, K.S.
4ee3651b-b672-4641-8f18-0b838e387620
Beckett, M.A.C.C., Horton, P.N., Hursthouse, M.B. and Varma, K.S.
(2007)
An unprecedented polyborate ester anion: X-ray diffraction studies on [1,8-C10H6(NMe2)(2)H][B5O6(OMe)(4)].
Inorganic Chemistry, 46 (10), .
(doi:10.1021/ic700433e).
Abstract
The slow hydrolysis of B(OMe)3 in a CH2Cl2 solution in the presence of 1,8-C10H6(NMe2)2 (5:1 ratio) led to the formation of the novel isolated pentaborate ester anion [B5O6(OMe)4]-, which was characterized by a single-crystal X-ray diffraction study as the salt [1,8-C10H6(NMe2)2H][B5O6(OMe)4].
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Published date: 2007
Keywords:
boric-acid, pentaborate, 1st examples, arylboronic acids
Identifiers
Local EPrints ID: 54243
URI: http://eprints.soton.ac.uk/id/eprint/54243
ISSN: 0020-1669
PURE UUID: 1a9aec10-6663-4bce-9349-290861f100ec
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Date deposited: 31 Jul 2008
Last modified: 16 Mar 2024 03:12
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Contributors
Author:
M.A.C.C. Beckett
Author:
P.N. Horton
Author:
K.S. Varma
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