fac,cis-bromidotricarbonylbis(tribenzylphosphine)rhenium(I)
fac,cis-bromidotricarbonylbis(tribenzylphosphine)rhenium(I)
Crystals of the title compound, fac,cis-[ReBr(C21H21P)2(CO)3], were obtained by recrystallization of a sample from CHCl3 layered with hexane. The geometry about the d6 ReI centre is (distorted) octahedral with the three CO ligands fac and the two tribenzylphosphine ligands cis. In accordance with the trans influence, the Re-C bond trans to Br is significantly shorter than those trans to the organophosphine ligands.
m785-m786
Beckett, M.A.
59bc94ea-6a41-48ac-9467-7638986fe34a
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Brassington, D.S.
22fc77cd-c713-4bf4-9b2c-969136d93429
Thornton-Pett, M.
b58df914-71e2-4eca-a381-3dc89cbe2663
2007
Beckett, M.A.
59bc94ea-6a41-48ac-9467-7638986fe34a
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Brassington, D.S.
22fc77cd-c713-4bf4-9b2c-969136d93429
Thornton-Pett, M.
b58df914-71e2-4eca-a381-3dc89cbe2663
Beckett, M.A., Light, M.E., Brassington, D.S. and Thornton-Pett, M.
(2007)
fac,cis-bromidotricarbonylbis(tribenzylphosphine)rhenium(I).
Acta Crystallographica Section E: Crystallographic Communications, 63, .
(doi:10.1107/S160053680700726X).
Abstract
Crystals of the title compound, fac,cis-[ReBr(C21H21P)2(CO)3], were obtained by recrystallization of a sample from CHCl3 layered with hexane. The geometry about the d6 ReI centre is (distorted) octahedral with the three CO ligands fac and the two tribenzylphosphine ligands cis. In accordance with the trans influence, the Re-C bond trans to Br is significantly shorter than those trans to the organophosphine ligands.
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Published date: 2007
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Local EPrints ID: 54244
URI: http://eprints.soton.ac.uk/id/eprint/54244
PURE UUID: bd6db25d-4a7e-4098-8cab-a2e1813686c2
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Date deposited: 31 Jul 2008
Last modified: 16 Mar 2024 03:04
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Author:
M.A. Beckett
Author:
D.S. Brassington
Author:
M. Thornton-Pett
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