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fac,cis-bromidotricarbonylbis(tribenzylphosphine)rhenium(I)

Record type: Article

Crystals of the title compound, fac,cis-[ReBr(C21H21P)2(CO)3], were obtained by recrystallization of a sample from CHCl3 layered with hexane. The geometry about the d6 ReI centre is (distorted) octa­hedral with the three CO ligands fac and the two tribenzyl­phosphine ligands cis. In accordance with the trans influence, the Re-C bond trans to Br is significantly shorter than those trans to the organophos­phine ligands.

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Citation

Beckett, M.A., Light, M.E., Brassington, D.S. and Thornton-Pett, M. (2007) fac,cis-bromidotricarbonylbis(tribenzylphosphine)rhenium(I) Acta Crystallographica Section E Crystallographic Communications, 63, m785-m786. (doi:10.1107/S160053680700726X).

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Published date: 2007

Identifiers

Local EPrints ID: 54244
URI: http://eprints.soton.ac.uk/id/eprint/54244
PURE UUID: bd6db25d-4a7e-4098-8cab-a2e1813686c2
ORCID for M.E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 31 Jul 2008
Last modified: 17 Jul 2017 14:36

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Contributors

Author: M.A. Beckett
Author: M.E. Light ORCID iD
Author: D.S. Brassington
Author: M. Thornton-Pett

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