fac,cis-bromidotricarbonylbis(tribenzylphosphine)rhenium(I)


Beckett, M.A., Light, M.E., Brassington, D.S. and Thornton-Pett, M. (2007) fac,cis-bromidotricarbonylbis(tribenzylphosphine)rhenium(I) Acta Crystallographica Section E Crystallographic Communications, 63, m785-m786. (doi:10.1107/S160053680700726X).

Download

[img] PDF sg2132 - Version of Record
Available under License Creative Commons Attribution.

Download (319kB)

Description/Abstract

Crystals of the title compound, fac,cis-[ReBr(C21H21P)2(CO)3], were obtained by recrystallization of a sample from CHCl3 layered with hexane. The geometry about the d6 ReI centre is (distorted) octa­hedral with the three CO ligands fac and the two tribenzyl­phosphine ligands cis. In accordance with the trans influence, the Re-C bond trans to Br is significantly shorter than those trans to the organophos­phine ligands.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1107/S160053680700726X
Subjects:
ePrint ID: 54244
Date :
Date Event
2007Published
Date Deposited: 31 Jul 2008
Last Modified: 16 Apr 2017 17:47
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/54244

Actions (login required)

View Item View Item