Reversible structural isomerisation in rare thioether complexes of cobalt(II)-effects of ligand architecture
Reversible structural isomerisation in rare thioether complexes of cobalt(II)-effects of ligand architecture
Rare examples of (high spin) Co(II) complexes with geometrically constrained tetrathioether ligands exhibit a very unusual structural isomerism, switching reversibly between tetrahedral monomers in solution and octahedral chain polymers in the solid; the crystal structures of one polymeric species and a tetrahedral monomer model compound are described.
chemistry, metal-complexes
1986-1988
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Manning, Joanna M.
071c4af0-0d09-422a-8ca3-d5a9454d587a
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Tsoureas, Nikolaos
b40771a1-8870-43bc-8989-3c6eee2f325f
Webster, Michael
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
2007
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Manning, Joanna M.
071c4af0-0d09-422a-8ca3-d5a9454d587a
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Tsoureas, Nikolaos
b40771a1-8870-43bc-8989-3c6eee2f325f
Webster, Michael
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
Evans, John, Levason, William, Manning, Joanna M., Reid, Gillian, Tsoureas, Nikolaos and Webster, Michael
(2007)
Reversible structural isomerisation in rare thioether complexes of cobalt(II)-effects of ligand architecture.
Dalton Transactions, (20), .
(doi:10.1039/b702792c).
Abstract
Rare examples of (high spin) Co(II) complexes with geometrically constrained tetrathioether ligands exhibit a very unusual structural isomerism, switching reversibly between tetrahedral monomers in solution and octahedral chain polymers in the solid; the crystal structures of one polymeric species and a tetrahedral monomer model compound are described.
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Published date: 2007
Keywords:
chemistry, metal-complexes
Identifiers
Local EPrints ID: 54291
URI: http://eprints.soton.ac.uk/id/eprint/54291
ISSN: 1477-9226
PURE UUID: 1e37d309-cc93-47bb-9ed6-e51079c4d7b7
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Date deposited: 31 Jul 2008
Last modified: 16 Mar 2024 02:43
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Contributors
Author:
Joanna M. Manning
Author:
Nikolaos Tsoureas
Author:
Michael Webster
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