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Polymorph VI of sulfapyridine: interpenetrating two- and three-dimensional hydrogen-bonded nets formed from two tautomeric forms

Polymorph VI of sulfapyridine: interpenetrating two- and three-dimensional hydrogen-bonded nets formed from two tautomeric forms
Polymorph VI of sulfapyridine: interpenetrating two- and three-dimensional hydrogen-bonded nets formed from two tautomeric forms
Polymorph VI of 4-amino-N-(2-pyridyl)benzenesulfonamide, C11H11N3O2S, is monoclinic (space group P21/n). The asymmetric unit contains two different tautomeric forms. The structure displays N-HN and N-HO hydrogen bonding. The two independent molecules form two separate two- and three-dimensional hydrogen-bonded networks which interpenetrate. The observed patterns of hydrogen bonding are analogous to those in polymorph I of sulfathiazole.
sulfathiazole, cambridge structural database, crystal-structures, 4-amino-n-2-pyridinylbenzenesulfonamide sulfapyridine
0108-2701
O323-O326
Gelbrich, T.
42309d69-eaf1-4bb7-ba2e-db61f338e370
Threlfall, T.L.
dc1fe3b2-c0c1-465c-942f-dbd4af68a37e
Bingham, A.L.
8349446d-f3ab-4a2c-9b7b-88b01a9f59c0
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Gelbrich, T.
42309d69-eaf1-4bb7-ba2e-db61f338e370
Threlfall, T.L.
dc1fe3b2-c0c1-465c-942f-dbd4af68a37e
Bingham, A.L.
8349446d-f3ab-4a2c-9b7b-88b01a9f59c0
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Gelbrich, T., Threlfall, T.L., Bingham, A.L. and Hursthouse, M.B. (2007) Polymorph VI of sulfapyridine: interpenetrating two- and three-dimensional hydrogen-bonded nets formed from two tautomeric forms. Acta Crystallographica Section C: Crystal Structure Communications, 63, O323-O326. (doi:10.1107/S0108270107017817).

Record type: Article

Abstract

Polymorph VI of 4-amino-N-(2-pyridyl)benzenesulfonamide, C11H11N3O2S, is monoclinic (space group P21/n). The asymmetric unit contains two different tautomeric forms. The structure displays N-HN and N-HO hydrogen bonding. The two independent molecules form two separate two- and three-dimensional hydrogen-bonded networks which interpenetrate. The observed patterns of hydrogen bonding are analogous to those in polymorph I of sulfathiazole.

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Published date: 2007
Keywords: sulfathiazole, cambridge structural database, crystal-structures, 4-amino-n-2-pyridinylbenzenesulfonamide sulfapyridine

Identifiers

Local EPrints ID: 54301
URI: http://eprints.soton.ac.uk/id/eprint/54301
ISSN: 0108-2701
PURE UUID: 5bae5324-cc04-4005-b766-abc0eb057caf

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Date deposited: 31 Jul 2008
Last modified: 15 Mar 2024 10:46

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Contributors

Author: T. Gelbrich
Author: T.L. Threlfall
Author: A.L. Bingham
Author: M.B. Hursthouse

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