Tris(dimethylamido)bis(dimethylamine) titanium(IV) chlorido-bis(dimethylamine)[tris (pentafluoro-phenyl) boron-amido][tris(pentafluorophenyl)boron-nitrido]-titanate(IV) toluene solvate
Tris(dimethylamido)bis(dimethylamine) titanium(IV) chlorido-bis(dimethylamine)[tris (pentafluoro-phenyl) boron-amido][tris(pentafluorophenyl)boron-nitrido]-titanate(IV) toluene solvate
The title ionic solid, [Ti(C2H6N)3(C2H7N)2][Ti(C18BF15N)(C18H2BF15N)Cl(C2H7N)2]·C7H8, (I), comprises a cation with three dimethylamide ligands in the equatorial plane and two dimethylamine ligands positioned axially in a trigonal-bipyramidal geometry about the central TiIV atom. The anion has a highly distorted octahedral structure. The two dimethylamine ligands are coordinated mutually trans. The chloride is trans to the tris(pentafluorophenyl)boron-amide, while the sixth coordination site is occupied by an ortho-F atom of the tris(pentafluorophenyl)boron-amide group in a trans disposition with respect to the tris(pentafluorophenyl)boron-nitride ligand. The most significant feature of the anion is the presence of an unprecedented terminal TiN moiety [1.665 (2) Å], stabilized by coordination to B(C6F5)3, with a TiN-B angle of 169.50 (19)°.
tris(pentafluorophenyl)boron, crystal-structure, derivatives, complexes, chemistry, perfluorophenyl, chemical-vapor-deposition, nitride, elements
M401-M404
Mountford, A.J.
5fa101dd-20e7-4daf-89a4-b94a795fa6fb
Lancaster, S.J.
35c9bf31-6e88-40b9-a0e7-c8968bb4d84a
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
2007
Mountford, A.J.
5fa101dd-20e7-4daf-89a4-b94a795fa6fb
Lancaster, S.J.
35c9bf31-6e88-40b9-a0e7-c8968bb4d84a
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Mountford, A.J., Lancaster, S.J. and Coles, S.J.
(2007)
Tris(dimethylamido)bis(dimethylamine) titanium(IV) chlorido-bis(dimethylamine)[tris (pentafluoro-phenyl) boron-amido][tris(pentafluorophenyl)boron-nitrido]-titanate(IV) toluene solvate.
Acta Crystallographica Section C: Crystal Structure Communications, 63, .
(doi:10.1107/S0108270107035238).
Abstract
The title ionic solid, [Ti(C2H6N)3(C2H7N)2][Ti(C18BF15N)(C18H2BF15N)Cl(C2H7N)2]·C7H8, (I), comprises a cation with three dimethylamide ligands in the equatorial plane and two dimethylamine ligands positioned axially in a trigonal-bipyramidal geometry about the central TiIV atom. The anion has a highly distorted octahedral structure. The two dimethylamine ligands are coordinated mutually trans. The chloride is trans to the tris(pentafluorophenyl)boron-amide, while the sixth coordination site is occupied by an ortho-F atom of the tris(pentafluorophenyl)boron-amide group in a trans disposition with respect to the tris(pentafluorophenyl)boron-nitride ligand. The most significant feature of the anion is the presence of an unprecedented terminal TiN moiety [1.665 (2) Å], stabilized by coordination to B(C6F5)3, with a TiN-B angle of 169.50 (19)°.
This record has no associated files available for download.
More information
Published date: 2007
Keywords:
tris(pentafluorophenyl)boron, crystal-structure, derivatives, complexes, chemistry, perfluorophenyl, chemical-vapor-deposition, nitride, elements
Identifiers
Local EPrints ID: 54349
URI: http://eprints.soton.ac.uk/id/eprint/54349
ISSN: 0108-2701
PURE UUID: a4122dab-1129-4a74-9704-18a8b94dd5eb
Catalogue record
Date deposited: 31 Jul 2008
Last modified: 16 Mar 2024 03:05
Export record
Altmetrics
Contributors
Author:
A.J. Mountford
Author:
S.J. Lancaster
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics
