A high-performance selective oxidation system for the facile production of fine chemicals
A high-performance selective oxidation system for the facile production of fine chemicals
MnIIIAlPO-5 and CrVIAlPO-5 redox (microporous) catalysts are effective, in the presence of dissolved acetylperoxyborate (APB) under mild conditions (333–373 K), and much superior to the titanosilicate, TS-1 (also a single-site heterogeneous catalyst), in the selective oxidation of primary, secondary, benzylic and other unsaturated alcohols, p-cymene, methyl cyclohexene and other speciality organics which are of value in the fine-chemical and pharmaceutical industries.
site heterogeneous catalysts, decomposition, cyclohexane, alcohols, molecular-oxygen, insight
1924-1926
Raja, R.
74faf442-38a6-4ac1-84f9-b3c039cb392b
Thomas, J.M.
98879775-7bc8-4aeb-89c1-da6c60c856c2
Greenhill-Hooper, M.
adb70765-f79b-4f1b-a739-77ea987e5c3f
Doukova, V.
22342089-ae84-4e87-8641-90599e1ce3c5
2007
Raja, R.
74faf442-38a6-4ac1-84f9-b3c039cb392b
Thomas, J.M.
98879775-7bc8-4aeb-89c1-da6c60c856c2
Greenhill-Hooper, M.
adb70765-f79b-4f1b-a739-77ea987e5c3f
Doukova, V.
22342089-ae84-4e87-8641-90599e1ce3c5
Raja, R., Thomas, J.M., Greenhill-Hooper, M. and Doukova, V.
(2007)
A high-performance selective oxidation system for the facile production of fine chemicals.
Chemical Communications, (19), .
(doi:10.1039/b618090f).
Abstract
MnIIIAlPO-5 and CrVIAlPO-5 redox (microporous) catalysts are effective, in the presence of dissolved acetylperoxyborate (APB) under mild conditions (333–373 K), and much superior to the titanosilicate, TS-1 (also a single-site heterogeneous catalyst), in the selective oxidation of primary, secondary, benzylic and other unsaturated alcohols, p-cymene, methyl cyclohexene and other speciality organics which are of value in the fine-chemical and pharmaceutical industries.
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Published date: 2007
Keywords:
site heterogeneous catalysts, decomposition, cyclohexane, alcohols, molecular-oxygen, insight
Identifiers
Local EPrints ID: 54373
URI: http://eprints.soton.ac.uk/id/eprint/54373
ISSN: 1359-7345
PURE UUID: a597b983-1fd5-47a2-9cf9-3eb06ff12b4c
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Date deposited: 31 Jul 2008
Last modified: 16 Mar 2024 03:51
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Contributors
Author:
J.M. Thomas
Author:
M. Greenhill-Hooper
Author:
V. Doukova
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