A high-performance selective oxidation system for the facile production of fine chemicals


Raja, R., Thomas, J.M., Greenhill-Hooper, M. and Doukova, V. (2007) A high-performance selective oxidation system for the facile production of fine chemicals Chemical Communications, (19), pp. 1924-1926. (doi:10.1039/b618090f).

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Description/Abstract

MnIIIAlPO-5 and CrVIAlPO-5 redox (microporous) catalysts are effective, in the presence of dissolved acetylperoxyborate (APB) under mild conditions (333–373 K), and much superior to the titanosilicate, TS-1 (also a single-site heterogeneous catalyst), in the selective oxidation of primary, secondary, benzylic and other unsaturated alcohols, p-cymene, methyl cyclohexene and other speciality organics which are of value in the fine-chemical and pharmaceutical industries.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1039/b618090f
ISSNs: 1359-7345 (print)
Keywords: site heterogeneous catalysts, decomposition, cyclohexane, alcohols, molecular-oxygen, insight
Subjects:
ePrint ID: 54373
Date :
Date Event
2007Published
Date Deposited: 31 Jul 2008
Last Modified: 16 Apr 2017 17:47
Further Information:Google Scholar
URI: http://eprints.soton.ac.uk/id/eprint/54373

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