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A high-performance selective oxidation system for the facile production of fine chemicals

Raja, R., Thomas, J.M., Greenhill-Hooper, M. and Doukova, V. (2007) A high-performance selective oxidation system for the facile production of fine chemicals Chemical Communications, (19), pp. 1924-1926. (doi:10.1039/b618090f).

Record type: Article

Abstract

MnIIIAlPO-5 and CrVIAlPO-5 redox (microporous) catalysts are effective, in the presence of dissolved acetylperoxyborate (APB) under mild conditions (333–373 K), and much superior to the titanosilicate, TS-1 (also a single-site heterogeneous catalyst), in the selective oxidation of primary, secondary, benzylic and other unsaturated alcohols, p-cymene, methyl cyclohexene and other speciality organics which are of value in the fine-chemical and pharmaceutical industries.

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More information

Published date: 2007
Keywords: site heterogeneous catalysts, decomposition, cyclohexane, alcohols, molecular-oxygen, insight

Identifiers

Local EPrints ID: 54373
URI: http://eprints.soton.ac.uk/id/eprint/54373
ISSN: 1359-7345
PURE UUID: a597b983-1fd5-47a2-9cf9-3eb06ff12b4c
ORCID for R. Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 31 Jul 2008
Last modified: 17 Jul 2017 14:35

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Contributors

Author: R. Raja ORCID iD
Author: J.M. Thomas
Author: M. Greenhill-Hooper
Author: V. Doukova

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