The regiochemistry of zirconacycle elaboration
The regiochemistry of zirconacycle elaboration
The regioselectivity of insertion of carbenoids into a variety of unsymmetrical zirconacyclopentanes is reported. For comparison the regioselectivities of isonitrile insertion and protonation have also been determined.
copper chloride, carbenoid, complexes, metallacycle transfer, convenient method, metal-promoted cyclization, diene cyclization, zirconocene, selective formation, zirconium chemistry, insertion, bond formation reaction
11686-11701
Thomas, Emma
69f1cb1a-8550-4194-9904-67f6d9535ff1
Dixon, Sally
943160fc-1b70-4c29-b2e3-b7785cee8a0c
Whitby, Richard J.
45632236-ab00-4ad0-a02d-6209043e818b
19 November 2007
Thomas, Emma
69f1cb1a-8550-4194-9904-67f6d9535ff1
Dixon, Sally
943160fc-1b70-4c29-b2e3-b7785cee8a0c
Whitby, Richard J.
45632236-ab00-4ad0-a02d-6209043e818b
Thomas, Emma, Dixon, Sally and Whitby, Richard J.
(2007)
The regiochemistry of zirconacycle elaboration.
Tetrahedron, 63 (47), .
(doi:10.1016/j.tet.2007.08.105).
Abstract
The regioselectivity of insertion of carbenoids into a variety of unsymmetrical zirconacyclopentanes is reported. For comparison the regioselectivities of isonitrile insertion and protonation have also been determined.
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Published date: 19 November 2007
Keywords:
copper chloride, carbenoid, complexes, metallacycle transfer, convenient method, metal-promoted cyclization, diene cyclization, zirconocene, selective formation, zirconium chemistry, insertion, bond formation reaction
Identifiers
Local EPrints ID: 54396
URI: http://eprints.soton.ac.uk/id/eprint/54396
ISSN: 0040-4020
PURE UUID: d55995f6-bb29-4aa2-b214-822292807af1
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Date deposited: 31 Jul 2008
Last modified: 16 Mar 2024 03:24
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Author:
Emma Thomas
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