Amoroso, A.J., Burrows, M.W., Coles, S.J., Haigh, R., Farley, R.D., Hursthouse, M.B., Jones, M., Malik, K.M.A. and Murphy, D.M.
The synthesis and structure of terpyridine-N-oxide complexes of copper(II) perchlorate
Dalton Transactions, 2008, (4), . (doi:10.1039/b713444d).
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The co-ordination of a series of terpyridine-N-oxide ligands to the Cu(II) ion is reported. Addition of two equivalents of ligand results in the formation of the expected 2 : 1 six co-ordinate product, while the addition of one equivalent of ligand allows the isolation of 1 : 1 species if the ligand has a meridonal binding mode. The five complexes isolated were characterised in the solid state by X-ray crystallography while they are studied in solution using EPR, UV-vis spectroscopy and IR spectroscopy.
|Digital Object Identifier (DOI):
||molecular-structure, 1'-dioxide, 2''-terpyridine 1, (s)-3, metal-complexes, 1''-trioxide, jahn-teller distortion, ray crystal-structure, n'-dioxide, 2, 1', 2', 3'-dimethyl-2, 2'-biquinoline n, coordination chemistry, mixed pyridine-phenol, magnetic-properties, 2'-bipyridine 1
||05 Aug 2008
||16 Apr 2017 17:47
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