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Selective binding of L-glutamate derivative in aqueous solvents

Selective binding of L-glutamate derivative in aqueous solvents
Selective binding of L-glutamate derivative in aqueous solvents
A chiral bisguanidinium macrocycle binds N-Boc-L-glutamate in a 1 : 1 stoichiometry with significant selectivity in competitive solvent (DMSO–H2O).
guanidinium, recognition, dicarboxylate anions, chemistry, anion receptor molecules, coordination, thermodynamic analysis, glutamate, protic solvents, n-protected, ditopic polyammonium macrocycles, cooperative interactions
1477-0520
2340-2345
Bartoli, S.
7954394a-dd77-4757-8fc3-fdaaab56b5cf
Mahmood, T.
a6b0cbe2-b2ba-4260-925d-f11765d4400c
Malik, A.
697af50e-7dfb-4e4e-815c-b39ae4e8ff7b
Dixon, S.
943160fc-1b70-4c29-b2e3-b7785cee8a0c
Kilburn, J.D.
266a563a-6076-4109-9436-1c66d0b02383
Bartoli, S.
7954394a-dd77-4757-8fc3-fdaaab56b5cf
Mahmood, T.
a6b0cbe2-b2ba-4260-925d-f11765d4400c
Malik, A.
697af50e-7dfb-4e4e-815c-b39ae4e8ff7b
Dixon, S.
943160fc-1b70-4c29-b2e3-b7785cee8a0c
Kilburn, J.D.
266a563a-6076-4109-9436-1c66d0b02383

Bartoli, S., Mahmood, T., Malik, A., Dixon, S. and Kilburn, J.D. (2008) Selective binding of L-glutamate derivative in aqueous solvents. Organic & Biomolecular Chemistry, 6 (13), 2340-2345. (doi:10.1039/b803089h).

Record type: Article

Abstract

A chiral bisguanidinium macrocycle binds N-Boc-L-glutamate in a 1 : 1 stoichiometry with significant selectivity in competitive solvent (DMSO–H2O).

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More information

Published date: 2008
Keywords: guanidinium, recognition, dicarboxylate anions, chemistry, anion receptor molecules, coordination, thermodynamic analysis, glutamate, protic solvents, n-protected, ditopic polyammonium macrocycles, cooperative interactions

Identifiers

Local EPrints ID: 54419
URI: https://eprints.soton.ac.uk/id/eprint/54419
ISSN: 1477-0520
PURE UUID: 8a6755b7-f57d-4e41-b433-4a1c795c62d2
ORCID for S. Dixon: ORCID iD orcid.org/0000-0003-2219-3635

Catalogue record

Date deposited: 05 Aug 2008
Last modified: 20 Jul 2019 01:04

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Contributors

Author: S. Bartoli
Author: T. Mahmood
Author: A. Malik
Author: S. Dixon ORCID iD
Author: J.D. Kilburn

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