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Fluorescent anthracene-based anion receptors

Fluorescent anthracene-based anion receptors
Fluorescent anthracene-based anion receptors
A variety of amide-substituted anthracene derivates have been synthesised and their anion complexation properties studied using 1H-NMR titration techniques. Additionally, bis-urea functionalised anthracene derivatives have been shown to serve as excellent receptors for oxo-anions and to function as sensors via fluorescence quenching in DMSO-d6/0.5% water and MeCN/DMSO (96.5:3.5 v/v).
coordination, ion-pair, carboxylate complexation, binding-sites, stability, anion receptors, fluorescence, solid-state, conformational control, crystallography, urea, transport, recognition
1061-0278
349-355
Brooks, S.J.
0cbd96c6-293b-4035-9a4b-013072ab7a84
Caltagirone, C.
85626041-fdae-4dd6-8a5c-9a15194f8b63
Cossins, A.J.
62aca190-2e0b-4898-884c-b7b9d03ba6cf
Gale, P.A.
c840b7e9-6847-4843-91af-fa0f8563d943
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Brooks, S.J.
0cbd96c6-293b-4035-9a4b-013072ab7a84
Caltagirone, C.
85626041-fdae-4dd6-8a5c-9a15194f8b63
Cossins, A.J.
62aca190-2e0b-4898-884c-b7b9d03ba6cf
Gale, P.A.
c840b7e9-6847-4843-91af-fa0f8563d943
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161

Brooks, S.J., Caltagirone, C., Cossins, A.J., Gale, P.A. and Light, M.E. (2008) Fluorescent anthracene-based anion receptors. Supramolecular Chemistry, 20 (4), 349-355. (doi:10.1080/10610270701258121).

Record type: Article

Abstract

A variety of amide-substituted anthracene derivates have been synthesised and their anion complexation properties studied using 1H-NMR titration techniques. Additionally, bis-urea functionalised anthracene derivatives have been shown to serve as excellent receptors for oxo-anions and to function as sensors via fluorescence quenching in DMSO-d6/0.5% water and MeCN/DMSO (96.5:3.5 v/v).

Full text not available from this repository.

More information

Published date: June 2008
Keywords: coordination, ion-pair, carboxylate complexation, binding-sites, stability, anion receptors, fluorescence, solid-state, conformational control, crystallography, urea, transport, recognition

Identifiers

Local EPrints ID: 54429
URI: https://eprints.soton.ac.uk/id/eprint/54429
ISSN: 1061-0278
PURE UUID: 02bebf31-0e0f-4b91-8d9f-bcc70f536558
ORCID for P.A. Gale: ORCID iD orcid.org/0000-0001-9751-4910
ORCID for M.E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 05 Aug 2008
Last modified: 12 Nov 2019 01:54

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