Fluorescent anthracene-based anion receptors
Fluorescent anthracene-based anion receptors
A variety of amide-substituted anthracene derivates have been synthesised and their anion complexation properties studied using 1H-NMR titration techniques. Additionally, bis-urea functionalised anthracene derivatives have been shown to serve as excellent receptors for oxo-anions and to function as sensors via fluorescence quenching in DMSO-d6/0.5% water and MeCN/DMSO (96.5:3.5 v/v).
coordination, ion-pair, carboxylate complexation, binding-sites, stability, anion receptors, fluorescence, solid-state, conformational control, crystallography, urea, transport, recognition
349-355
Brooks, S.J.
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Caltagirone, C.
85626041-fdae-4dd6-8a5c-9a15194f8b63
Cossins, A.J.
62aca190-2e0b-4898-884c-b7b9d03ba6cf
Gale, P.A.
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Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
June 2008
Brooks, S.J.
90e62b94-2814-4683-8ad8-4f0cd391580e
Caltagirone, C.
85626041-fdae-4dd6-8a5c-9a15194f8b63
Cossins, A.J.
62aca190-2e0b-4898-884c-b7b9d03ba6cf
Gale, P.A.
c840b7e9-6847-4843-91af-fa0f8563d943
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Brooks, S.J., Caltagirone, C., Cossins, A.J., Gale, P.A. and Light, M.E.
(2008)
Fluorescent anthracene-based anion receptors.
Supramolecular Chemistry, 20 (4), .
(doi:10.1080/10610270701258121).
Abstract
A variety of amide-substituted anthracene derivates have been synthesised and their anion complexation properties studied using 1H-NMR titration techniques. Additionally, bis-urea functionalised anthracene derivatives have been shown to serve as excellent receptors for oxo-anions and to function as sensors via fluorescence quenching in DMSO-d6/0.5% water and MeCN/DMSO (96.5:3.5 v/v).
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More information
Published date: June 2008
Keywords:
coordination, ion-pair, carboxylate complexation, binding-sites, stability, anion receptors, fluorescence, solid-state, conformational control, crystallography, urea, transport, recognition
Identifiers
Local EPrints ID: 54429
URI: http://eprints.soton.ac.uk/id/eprint/54429
ISSN: 1061-0278
PURE UUID: 02bebf31-0e0f-4b91-8d9f-bcc70f536558
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Date deposited: 05 Aug 2008
Last modified: 16 Mar 2024 03:16
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Contributors
Author:
S.J. Brooks
Author:
C. Caltagirone
Author:
A.J. Cossins
Author:
P.A. Gale
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