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On the highly stereoselective addition of lithio-acetylides to alpha-hydroxy-ketones

On the highly stereoselective addition of lithio-acetylides to alpha-hydroxy-ketones
On the highly stereoselective addition of lithio-acetylides to alpha-hydroxy-ketones
Addition of 2 equiv of a lithio-acetylide to an unprotected ?-hydroxy ketone is extremely stereoselective in examples where the two ketone substituents are relatively large.
5-endo-dig cyclizations, beta-iodofurans
0040-4039
2240-2242
Dunford, D.
378dc511-3641-43a7-8a8d-449545c8c56d
Guyader, M.
c3a54c84-c54b-4399-8894-d72f2e51abd9
Jones, S.
43516f9c-c999-4c10-86b6-43992e4e7a29
Knight, D.W.
dbe05fb8-fea1-4e2e-8555-0c72c3f5bc65
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Dunford, D.
378dc511-3641-43a7-8a8d-449545c8c56d
Guyader, M.
c3a54c84-c54b-4399-8894-d72f2e51abd9
Jones, S.
43516f9c-c999-4c10-86b6-43992e4e7a29
Knight, D.W.
dbe05fb8-fea1-4e2e-8555-0c72c3f5bc65
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8

Dunford, D., Guyader, M., Jones, S., Knight, D.W., Hursthouse, M.B. and Coles, S.J. (2008) On the highly stereoselective addition of lithio-acetylides to alpha-hydroxy-ketones. Tetrahedron Letters, 49 (14), 2240-2242. (doi:10.1016/j.tetlet.2008.02.032).

Record type: Article

Abstract

Addition of 2 equiv of a lithio-acetylide to an unprotected ?-hydroxy ketone is extremely stereoselective in examples where the two ketone substituents are relatively large.

Full text not available from this repository.

More information

Published date: 31 March 2008
Keywords: 5-endo-dig cyclizations, beta-iodofurans

Identifiers

Local EPrints ID: 54445
URI: http://eprints.soton.ac.uk/id/eprint/54445
ISSN: 0040-4039
PURE UUID: dfbf8123-b902-44c2-a035-ae3b1a999b1e
ORCID for S.J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 05 Aug 2008
Last modified: 20 Jul 2019 01:09

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