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A comparative study on chemiluminescence properties of some inorganic systems

A comparative study on chemiluminescence properties of some inorganic systems
A comparative study on chemiluminescence properties of some inorganic systems
Chemiluminescence (CL) of selected inorganic reaction systems, generating ultraweak photonemission, has been studied. The kinetics of the systems and their emission spectra have been characterisedby measurements with the use of the stationary and the flow methods of CL recording. The systems studiedcontained cations at different oxidation degree such as Fe2+\3+, Cu+\2+, Co2+\3+, Eu2+\3+, CLO- anions and hydrogen peroxide without organic sensitisers. On the basis of the analysis of the spectra, in particularsystems emitters have been identified and mechanisms of the reactions have been proposed. The effectof carbonate and azide ions and propylene carbonate on the yield of CL and spectral characterisationof the systems studied has been evidenced and discussed. A possibility of the application of the systems Eu3+\N3- \H2O2 and Co2+\propylene carbonate\H2O2 for analytical purposes has been considered.
1110-662X
239-242
Elbanowski, Marian
75a349f5-6192-4cca-b9c5-a09109959187
Staninski, Krzysztof
47d9f6db-e6bd-4e8b-af17-3ff736b78b48
Kaczmarek, Małgorzata
408ec59b-8dba-41c1-89d0-af846d1bf327
Lis, Stefan
bb4af651-568f-43d5-9418-ff4b925156bb
Elbanowski, Marian
75a349f5-6192-4cca-b9c5-a09109959187
Staninski, Krzysztof
47d9f6db-e6bd-4e8b-af17-3ff736b78b48
Kaczmarek, Małgorzata
408ec59b-8dba-41c1-89d0-af846d1bf327
Lis, Stefan
bb4af651-568f-43d5-9418-ff4b925156bb

Elbanowski, Marian, Staninski, Krzysztof, Kaczmarek, Małgorzata and Lis, Stefan (2003) A comparative study on chemiluminescence properties of some inorganic systems. International Journal of Photoenergy, 5 (4), 239-242. (doi:10.1155/S1110662X03000382).

Record type: Article

Abstract

Chemiluminescence (CL) of selected inorganic reaction systems, generating ultraweak photonemission, has been studied. The kinetics of the systems and their emission spectra have been characterisedby measurements with the use of the stationary and the flow methods of CL recording. The systems studiedcontained cations at different oxidation degree such as Fe2+\3+, Cu+\2+, Co2+\3+, Eu2+\3+, CLO- anions and hydrogen peroxide without organic sensitisers. On the basis of the analysis of the spectra, in particularsystems emitters have been identified and mechanisms of the reactions have been proposed. The effectof carbonate and azide ions and propylene carbonate on the yield of CL and spectral characterisationof the systems studied has been evidenced and discussed. A possibility of the application of the systems Eu3+\N3- \H2O2 and Co2+\propylene carbonate\H2O2 for analytical purposes has been considered.

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Published date: 2003

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Local EPrints ID: 57185
URI: https://eprints.soton.ac.uk/id/eprint/57185
ISSN: 1110-662X
PURE UUID: 3ca079aa-84e5-4105-9fd1-02f1903632f9

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Date deposited: 14 Aug 2008
Last modified: 19 Jul 2019 18:41

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