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Well-dispersed single-walled carbon nanotube/polyaniline composite films

Well-dispersed single-walled carbon nanotube/polyaniline composite films
Well-dispersed single-walled carbon nanotube/polyaniline composite films
Single-walled carbon nanotube (SWNT) / polyaniline (PANI) composite films with good uniformity and dispersion were prepared by electrochemical polymerization of aniline containing well-dissolved SWNTs. The results of atomic force microscopy (AFM) and UV–Vis adsorption spectroscopy show that aniline can be used to solubilize SWNTs via formation of donor–acceptor complexes. The electrochemical deposition of SWNT–aniline solutions have been investigated by cyclic voltammetry. The results show that SWNT-based aniline solutions exhibit a drastic increase in peak current within the potential scanning region. The doping effect of SWNTs on PANI films was investigated by electrochemistry and FTIR spectroscopy. The results indicate that the enhanced electroactivity and conductivity of the SWNT/PANI composite films may be due to the strong interaction between SWNTs and PANI, which facilitates the effective degree of electron delocalization.
carbon nanotubes, infrared spectroscopy, scanning electron microscopy
0008-6223
2731-2736
Huang, Ji-Er
7e27ecba-a867-424b-917e-9782b2ed4c9c
Li, Xiao-Hong
ea8135d4-1bd7-4771-85cd-eb8f2a264654
Xu, Ji-Chuan
04bf4fe9-49f8-4014-85e4-f8128abae986
Li, Hu-Lin
27f91740-1583-4709-80fe-f443e9c08a2b
Huang, Ji-Er
7e27ecba-a867-424b-917e-9782b2ed4c9c
Li, Xiao-Hong
ea8135d4-1bd7-4771-85cd-eb8f2a264654
Xu, Ji-Chuan
04bf4fe9-49f8-4014-85e4-f8128abae986
Li, Hu-Lin
27f91740-1583-4709-80fe-f443e9c08a2b

Huang, Ji-Er, Li, Xiao-Hong, Xu, Ji-Chuan and Li, Hu-Lin (2003) Well-dispersed single-walled carbon nanotube/polyaniline composite films. Carbon, 41 (14), 2731-2736. (doi:10.1016/S0008-6223(03)00359-2).

Record type: Article

Abstract

Single-walled carbon nanotube (SWNT) / polyaniline (PANI) composite films with good uniformity and dispersion were prepared by electrochemical polymerization of aniline containing well-dissolved SWNTs. The results of atomic force microscopy (AFM) and UV–Vis adsorption spectroscopy show that aniline can be used to solubilize SWNTs via formation of donor–acceptor complexes. The electrochemical deposition of SWNT–aniline solutions have been investigated by cyclic voltammetry. The results show that SWNT-based aniline solutions exhibit a drastic increase in peak current within the potential scanning region. The doping effect of SWNTs on PANI films was investigated by electrochemistry and FTIR spectroscopy. The results indicate that the enhanced electroactivity and conductivity of the SWNT/PANI composite films may be due to the strong interaction between SWNTs and PANI, which facilitates the effective degree of electron delocalization.

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More information

Published date: 2003
Keywords: carbon nanotubes, infrared spectroscopy, scanning electron microscopy
Organisations: Engineering Mats & Surface Engineerg Gp

Identifiers

Local EPrints ID: 63262
URI: http://eprints.soton.ac.uk/id/eprint/63262
ISSN: 0008-6223
PURE UUID: 9a2265f0-c545-4db0-9baa-14293599a6a8

Catalogue record

Date deposited: 25 Sep 2008
Last modified: 15 Mar 2024 11:37

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Contributors

Author: Ji-Er Huang
Author: Xiao-Hong Li
Author: Ji-Chuan Xu
Author: Hu-Lin Li

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