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Electrochemical study of Co(II)/Co(III) on different electrode materials for energy storage in redox flow cells

Electrochemical study of Co(II)/Co(III) on different electrode materials for energy storage in redox flow cells
Electrochemical study of Co(II)/Co(III) on different electrode materials for energy storage in redox flow cells
The development of redox flow cells has been carried out through the use of several redox couples which oxidize and reduce to store electrical energy. Some problems encountered in redox cells include: low solubility of redox couples, slow kinetics, low stability of electrode materials and high toxicity of electroactive species. In this paper, Co(III)/Co(II) has been investigated as a possible electroactive material because of its high oxidizing power and the relatively low toxicity of Co(III). The electrochemical study of Co(III)/Co(II) was carried out on different electrode materials such as glassy carbon, Au, Pt, Pb and stainless steel. Results show that the high oxidizing power of Co(III) does not enable to observe its reduction reaction in the aforementioned electrode materials possibly due to electrode surface corrosion and/or water oxidation. However, the electrolysis of Co(III) with a Pb electrode shows that the system is reversible and forms PbO2 on the electrode surface
redox flow cells, energy storage
1938-5862
237-247
López-Estrada, Salvador A
008b7a00-f685-489b-9bbd-7e94dd51b4ae
Alatorre-Ordaz, Alejandro
d8a46de7-b527-4e8e-bd6f-418d544183de
Gutiérrez-Granados, Silvia
68d17d87-c675-4fac-9354-9230424a34b6
Ponce de Leon, Carlos
508a312e-75ff-4bcb-9151-dacc424d755c
Walsh, Franck C.
309528e7-062e-439b-af40-9309bc91efb2
López-Estrada, Salvador A
008b7a00-f685-489b-9bbd-7e94dd51b4ae
Alatorre-Ordaz, Alejandro
d8a46de7-b527-4e8e-bd6f-418d544183de
Gutiérrez-Granados, Silvia
68d17d87-c675-4fac-9354-9230424a34b6
Ponce de Leon, Carlos
508a312e-75ff-4bcb-9151-dacc424d755c
Walsh, Franck C.
309528e7-062e-439b-af40-9309bc91efb2

López-Estrada, Salvador A, Alatorre-Ordaz, Alejandro, Gutiérrez-Granados, Silvia, Ponce de Leon, Carlos and Walsh, Franck C. (2009) Electrochemical study of Co(II)/Co(III) on different electrode materials for energy storage in redox flow cells. ECS Transactions, 20 (1), 237-247. (doi:10.1149/1.3268391).

Record type: Article

Abstract

The development of redox flow cells has been carried out through the use of several redox couples which oxidize and reduce to store electrical energy. Some problems encountered in redox cells include: low solubility of redox couples, slow kinetics, low stability of electrode materials and high toxicity of electroactive species. In this paper, Co(III)/Co(II) has been investigated as a possible electroactive material because of its high oxidizing power and the relatively low toxicity of Co(III). The electrochemical study of Co(III)/Co(II) was carried out on different electrode materials such as glassy carbon, Au, Pt, Pb and stainless steel. Results show that the high oxidizing power of Co(III) does not enable to observe its reduction reaction in the aforementioned electrode materials possibly due to electrode surface corrosion and/or water oxidation. However, the electrolysis of Co(III) with a Pb electrode shows that the system is reversible and forms PbO2 on the electrode surface

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More information

Published date: 2009
Additional Information: 24th Meeting of The Mexican Electrochemical Society and 2nd Meeting of the Mexican Section of the Electrochemical Society, May 31 - June 5, 2009 , Puerto Vallarta, Mexico MES 24: Electrochemical Applications to Biology, Nanotechnology, and Environmental Engineering and Materials Editor(s): M. Palomar-Pardavé, I. Gonzales, M. Romero-Romo, N. Casillas, M. Soto
Keywords: redox flow cells, energy storage
Organisations: Engineering Mats & Surface Engineerg Gp

Identifiers

Local EPrints ID: 69889
URI: https://eprints.soton.ac.uk/id/eprint/69889
ISSN: 1938-5862
PURE UUID: 0a803734-2af1-453b-bab0-361c843e0217
ORCID for Carlos Ponce de Leon: ORCID iD orcid.org/0000-0002-1907-5913

Catalogue record

Date deposited: 09 Dec 2009
Last modified: 06 Jun 2018 12:42

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