Designing experiments for an application in laser and surface Chemistry
Designing experiments for an application in laser and surface Chemistry
We consider the design used to collect data for a Second Harmonic Generation (SHG) experiment, where the behaviour of interfaces between two phases, for example the surface of a liquid, is investigated. These studies have implications in surfactants, catalysis, membranes and electrochemistry. Ongoing work will be described in designing experiments to investigate nonlinear models used to represent the data, relating the intensity of the SHG signal to the polarisation angles of the polarised light beam. The choice of design points and their effect on parameter estimates is investigated. Various designs and the current practice of using equal-spaced levels are investigated, and their relative merits compared on the basis of the overall aim of the chemical study.
design of experiments, nonlinear models, second harmonic generation
Mansson, Ralph A.
ae4c5cab-cfd5-4b27-81ae-be8e180cf81e
Welsh, Alan H.
71e0487b-c019-4405-ae36-59344e063ff5
Frey, Jeremy G.
ba60c559-c4af-44f1-87e6-ce69819bf23f
Danos, Lefteris
c831e137-37b9-42cc-ab8c-49de31038922
16 May 2003
Mansson, Ralph A.
ae4c5cab-cfd5-4b27-81ae-be8e180cf81e
Welsh, Alan H.
71e0487b-c019-4405-ae36-59344e063ff5
Frey, Jeremy G.
ba60c559-c4af-44f1-87e6-ce69819bf23f
Danos, Lefteris
c831e137-37b9-42cc-ab8c-49de31038922
Mansson, Ralph A., Welsh, Alan H., Frey, Jeremy G. and Danos, Lefteris
(2003)
Designing experiments for an application in laser and surface Chemistry.
Conference on New Directions in Experimental Design DAE 2003, Chicago, Illinois, USA.
14 - 17 May 2003.
Record type:
Conference or Workshop Item
(Poster)
Abstract
We consider the design used to collect data for a Second Harmonic Generation (SHG) experiment, where the behaviour of interfaces between two phases, for example the surface of a liquid, is investigated. These studies have implications in surfactants, catalysis, membranes and electrochemistry. Ongoing work will be described in designing experiments to investigate nonlinear models used to represent the data, relating the intensity of the SHG signal to the polarisation angles of the polarised light beam. The choice of design points and their effect on parameter estimates is investigated. Various designs and the current practice of using equal-spaced levels are investigated, and their relative merits compared on the basis of the overall aim of the chemical study.
Text
SHGexperiments.pdf
- Other
More information
Published date: 16 May 2003
Venue - Dates:
Conference on New Directions in Experimental Design DAE 2003, Chicago, Illinois, USA, 2003-05-14 - 2003-05-17
Keywords:
design of experiments, nonlinear models, second harmonic generation
Organisations:
Statistics
Identifiers
Local EPrints ID: 9579
URI: http://eprints.soton.ac.uk/id/eprint/9579
PURE UUID: af762d80-c04e-4622-9fc9-1aa2eeae0638
Catalogue record
Date deposited: 06 Oct 2004
Last modified: 16 Mar 2024 02:34
Export record
Contributors
Author:
Ralph A. Mansson
Author:
Alan H. Welsh
Author:
Lefteris Danos
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics
