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An investigation of the electrical, mechanical and thermal properties of petroleum-based and bio-based polypropylene

An investigation of the electrical, mechanical and thermal properties of petroleum-based and bio-based polypropylene
An investigation of the electrical, mechanical and thermal properties of petroleum-based and bio-based polypropylene
Growing environmental concerns have accelerated the adoption of sustainable materials across the plastic manufacturing sector. Polypropylene (PP) is a prevalent material in plastics due to its versatile properties and practical applications. Yet, the production of traditional PP requires the depletion of fossil fuel. This investigation compares the properties of a bio-derived chemically identical PP (Bio-PP), and a traditional petroleum-based PP (iPP). Three sample groups were manufactured, including iPP, Bio-PP and a 50:50 mixture of the two materials. Samples were studied by chemical, mechanical, thermal, and electrical characterization. The results show no significant difference in melting temperatures and an increase in crystallisation temperatures with the addition of Bio-PP as well as a decrease in the Young’s Modulus. iPP shows relatively lower dielectric permittivity and higher DC breakdown than its bio-based counterpart. These behavioral differences are likely to be due to the contrast in average molecular weight as well as bio-based effects.
IEEE
Khan, Ibrahim
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Callender, George
4189d79e-34c3-422c-a601-95b156c27e76
Andritsch, Thomas
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Saeedi, Istebreq
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Khan, Ibrahim
0f3a7d01-577f-49c0-88c5-f2060d151f5f
Callender, George
4189d79e-34c3-422c-a601-95b156c27e76
Andritsch, Thomas
8681e640-e584-424e-a1f1-0d8b713de01c
Saeedi, Istebreq
6df4dfcf-9bb8-4edc-952e-ccc4841f7b54

Khan, Ibrahim, Callender, George, Andritsch, Thomas and Saeedi, Istebreq (2026) An investigation of the electrical, mechanical and thermal properties of petroleum-based and bio-based polypropylene. In 6th International Conference on Dielectrics. IEEE.. (In Press)

Record type: Conference or Workshop Item (Paper)

Abstract

Growing environmental concerns have accelerated the adoption of sustainable materials across the plastic manufacturing sector. Polypropylene (PP) is a prevalent material in plastics due to its versatile properties and practical applications. Yet, the production of traditional PP requires the depletion of fossil fuel. This investigation compares the properties of a bio-derived chemically identical PP (Bio-PP), and a traditional petroleum-based PP (iPP). Three sample groups were manufactured, including iPP, Bio-PP and a 50:50 mixture of the two materials. Samples were studied by chemical, mechanical, thermal, and electrical characterization. The results show no significant difference in melting temperatures and an increase in crystallisation temperatures with the addition of Bio-PP as well as a decrease in the Young’s Modulus. iPP shows relatively lower dielectric permittivity and higher DC breakdown than its bio-based counterpart. These behavioral differences are likely to be due to the contrast in average molecular weight as well as bio-based effects.

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Accepted/In Press date: 16 April 2026
Venue - Dates: 6th IEEE International Conference on Dielectrics, , Southampton, United Kingdom, 2026-06-21 - 2026-06-25

Identifiers

Local EPrints ID: 513943
URI: https://eprints.soton.ac.uk/id/eprint/513943
PURE UUID: e9822682-9583-4753-aabf-c485c00a7f8d
ORCID for Thomas Andritsch: ORCID iD orcid.org/0000-0002-3462-022X
ORCID for Istebreq Saeedi: ORCID iD orcid.org/0000-0002-1254-748X

Catalogue record

Date deposited: 02 Sep 2026 16:45
Last modified: 13 Sep 2026 15:51

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Contributors

Author: Ibrahim Khan
Author: George Callender
Author: Thomas Andritsch ORCID iD
Author: Istebreq Saeedi ORCID iD

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