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Self-assembly of a “double dynamic covalent” amphiphile featuring a glucose-responsive imine bond

Self-assembly of a “double dynamic covalent” amphiphile featuring a glucose-responsive imine bond
Self-assembly of a “double dynamic covalent” amphiphile featuring a glucose-responsive imine bond
Glucose binding via boronate ester linkages selectively triggers imine bond formation between 4-formylphenylboronic acid and octylamine, leading to the formation of vesicular aggregates in aqueous solutions. This “double dynamic covalent assembly” allows the facile selective sensing of glucose against the otherwise serious interferant fructose, without the need to resort to synthetic effort.
1359-7345
6981-6984
Wu, Xin
65360fe8-d25a-4652-b7e4-40d513b57e7e
Chen, Xuan-Xuan
de54fe46-fb3e-42e0-9b80-0e5f8c9ae53d
Zhang, Miao
758c9654-752e-477a-a5b2-45f7873aa3e5
Li, Zhao
422810ea-1f91-43ec-ab21-5e2eb969bfea
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Jiang, Yun-Bao
d7717409-7411-4027-97ce-218de4ff6b18
Wu, Xin
65360fe8-d25a-4652-b7e4-40d513b57e7e
Chen, Xuan-Xuan
de54fe46-fb3e-42e0-9b80-0e5f8c9ae53d
Zhang, Miao
758c9654-752e-477a-a5b2-45f7873aa3e5
Li, Zhao
422810ea-1f91-43ec-ab21-5e2eb969bfea
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Jiang, Yun-Bao
d7717409-7411-4027-97ce-218de4ff6b18

Wu, Xin, Chen, Xuan-Xuan, Zhang, Miao, Li, Zhao, Gale, Philip A. and Jiang, Yun-Bao (2016) Self-assembly of a “double dynamic covalent” amphiphile featuring a glucose-responsive imine bond. Chemical Communications, 2016 (43), 6981-6984. (doi:10.1039/C6CC03167F).

Record type: Article

Abstract

Glucose binding via boronate ester linkages selectively triggers imine bond formation between 4-formylphenylboronic acid and octylamine, leading to the formation of vesicular aggregates in aqueous solutions. This “double dynamic covalent assembly” allows the facile selective sensing of glucose against the otherwise serious interferant fructose, without the need to resort to synthetic effort.

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Accepted/In Press date: 21 April 2016
e-pub ahead of print date: 21 April 2016
Published date: 28 May 2016
Organisations: Organic Chemistry: SCF

Identifiers

Local EPrints ID: 393206
URI: http://eprints.soton.ac.uk/id/eprint/393206
DOI: doi:10.1039/C6CC03167F
ISSN: 1359-7345
PURE UUID: 3da852ad-e481-4652-b41e-718c081549ad
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

Catalogue record

Date deposited: 22 Apr 2016 12:41
Last modified: 15 Mar 2024 05:31

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Contributors

Author: Xin Wu
Author: Xuan-Xuan Chen
Author: Miao Zhang
Author: Zhao Li
Author: Philip A. Gale ORCID iD
Author: Yun-Bao Jiang

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